Matches in SemOpenAlex for { <https://semopenalex.org/work/W2775449534> ?p ?o ?g. }
- W2775449534 abstract "Chemical modifications of the magnetic metal organic framework (MOF) Cu9X2(cpa)6·42H2O (X = F, Cl, Br; cpa = anion of 2-carboxypentonicacid) have been investigated as a means of modifying, in a tunable manner, the magnetism of this 2-D material best described as a triangles-in-triangles (TIT) or triangulated-Kagomé-latttice (TKL). Since numerous theoretical studies have already attempted to describe the enigmatic ground state of this Heisenberg lattice, tunable chemical modifications should provide an excellent opportunity to expand this class of materials for studies concerning fundamental physics of frustrated spins, and applications such as adiabatic demagnetization refrigeration (ADR) that depend on the magnetocaloric effect (MCE). The chemical modification investigated is the intercalation of d- and f-orbital ions into the voids of the framework (channels of nearly 20 Å diameter). Magnetic measurements in the temperature range 1.8 – 300 K confirm signature features of TKL magnetism in intercalated samples persist, specifically: i) large negative Weiss constant (θCW); ii) absence of a phase transition down to 1.8 K; iii) minimum in χMT; iv) low temperature χMT values increasingly divergent at low fields indicating net ferromagnetic correlations; and, v) increasing field dependence of magnetization at low temperatures suggestive of intermediate plateaus, or ferrimagnetism, not saturation." @default.
- W2775449534 created "2017-12-22" @default.
- W2775449534 creator A5017412612 @default.
- W2775449534 creator A5026752114 @default.
- W2775449534 creator A5058742708 @default.
- W2775449534 creator A5082604124 @default.
- W2775449534 date "2017-12-05" @default.
- W2775449534 modified "2023-09-23" @default.
- W2775449534 title "Metal organic framework Cu<sub>9</sub>Cl<sub>2</sub>(cpa)<sub>6</sub> as tunable molecular magnet" @default.
- W2775449534 cites W1606289159 @default.
- W2775449534 cites W1876287769 @default.
- W2775449534 cites W1966283535 @default.
- W2775449534 cites W1966991988 @default.
- W2775449534 cites W1972115244 @default.
- W2775449534 cites W1974973549 @default.
- W2775449534 cites W1981112140 @default.
- W2775449534 cites W1983024449 @default.
- W2775449534 cites W1987296369 @default.
- W2775449534 cites W1990355017 @default.
- W2775449534 cites W1990960555 @default.
- W2775449534 cites W1994537855 @default.
- W2775449534 cites W1996617562 @default.
- W2775449534 cites W2009749005 @default.
- W2775449534 cites W2015557350 @default.
- W2775449534 cites W2033160412 @default.
- W2775449534 cites W2041200382 @default.
- W2775449534 cites W2042876452 @default.
- W2775449534 cites W2043384372 @default.
- W2775449534 cites W2051067342 @default.
- W2775449534 cites W2061654580 @default.
- W2775449534 cites W2061886399 @default.
- W2775449534 cites W2068331778 @default.
- W2775449534 cites W2071812612 @default.
- W2775449534 cites W2083346617 @default.
- W2775449534 cites W2091296987 @default.
- W2775449534 cites W2114373473 @default.
- W2775449534 cites W2152038849 @default.
- W2775449534 cites W2158391865 @default.
- W2775449534 cites W2180864565 @default.
- W2775449534 cites W2257477164 @default.
- W2775449534 cites W2319257958 @default.
- W2775449534 cites W2495129751 @default.
- W2775449534 cites W2527928157 @default.
- W2775449534 cites W2535048027 @default.
- W2775449534 cites W2558616920 @default.
- W2775449534 cites W2589065346 @default.
- W2775449534 cites W4292328876 @default.
- W2775449534 doi "https://doi.org/10.1063/1.5006791" @default.
- W2775449534 hasPublicationYear "2017" @default.
- W2775449534 type Work @default.
- W2775449534 sameAs 2775449534 @default.
- W2775449534 citedByCount "7" @default.
- W2775449534 countsByYear W27754495342018 @default.
- W2775449534 countsByYear W27754495342019 @default.
- W2775449534 countsByYear W27754495342020 @default.
- W2775449534 countsByYear W27754495342023 @default.
- W2775449534 crossrefType "journal-article" @default.
- W2775449534 hasAuthorship W2775449534A5017412612 @default.
- W2775449534 hasAuthorship W2775449534A5026752114 @default.
- W2775449534 hasAuthorship W2775449534A5058742708 @default.
- W2775449534 hasAuthorship W2775449534A5082604124 @default.
- W2775449534 hasBestOaLocation W27754495341 @default.
- W2775449534 hasConcept C109663097 @default.
- W2775449534 hasConcept C115260700 @default.
- W2775449534 hasConcept C121332964 @default.
- W2775449534 hasConcept C137824038 @default.
- W2775449534 hasConcept C16889073 @default.
- W2775449534 hasConcept C179104552 @default.
- W2775449534 hasConcept C185592680 @default.
- W2775449534 hasConcept C186116631 @default.
- W2775449534 hasConcept C192562407 @default.
- W2775449534 hasConcept C197162081 @default.
- W2775449534 hasConcept C26873012 @default.
- W2775449534 hasConcept C32546565 @default.
- W2775449534 hasConcept C62520636 @default.
- W2775449534 hasConcept C779372 @default.
- W2775449534 hasConcept C82217956 @default.
- W2775449534 hasConcept C97355855 @default.
- W2775449534 hasConceptScore W2775449534C109663097 @default.
- W2775449534 hasConceptScore W2775449534C115260700 @default.
- W2775449534 hasConceptScore W2775449534C121332964 @default.
- W2775449534 hasConceptScore W2775449534C137824038 @default.
- W2775449534 hasConceptScore W2775449534C16889073 @default.
- W2775449534 hasConceptScore W2775449534C179104552 @default.
- W2775449534 hasConceptScore W2775449534C185592680 @default.
- W2775449534 hasConceptScore W2775449534C186116631 @default.
- W2775449534 hasConceptScore W2775449534C192562407 @default.
- W2775449534 hasConceptScore W2775449534C197162081 @default.
- W2775449534 hasConceptScore W2775449534C26873012 @default.
- W2775449534 hasConceptScore W2775449534C32546565 @default.
- W2775449534 hasConceptScore W2775449534C62520636 @default.
- W2775449534 hasConceptScore W2775449534C779372 @default.
- W2775449534 hasConceptScore W2775449534C82217956 @default.
- W2775449534 hasConceptScore W2775449534C97355855 @default.
- W2775449534 hasFunder F4320308695 @default.
- W2775449534 hasIssue "5" @default.
- W2775449534 hasLocation W27754495341 @default.
- W2775449534 hasOpenAccess W2775449534 @default.
- W2775449534 hasPrimaryLocation W27754495341 @default.
- W2775449534 hasRelatedWork W1492517117 @default.