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- W2775476645 abstract "This paper reports the preparation of mixed matrix membranes (MMMs) by incorporating a two-dimensional zeolitic imidazolate framework-L (ZIF-L) into a highly gas permeable hydroxyl group-containing polyimide (PI) for hydrogen separation. ZIF-L has a leaf-shaped morphology with excellent CO2 adsorption properties due to strong interaction between ZIF-L and CO2 molecules. The dispersion of ZIF-L crystals in the polymer phase increased CO2 adsorption and restricted CO2 transport through MMMs, resulting in a significant increase of H2 selectivity over CO2. The gas transport properties of MMMs with a ZIF-L loading up to 20 wt% were investigated, and the results showed such MMMs had a H2 permeability of 260 Barrers and ideal H2/CO2 selectivity of 13.4 at room temperature. The membranes presented here have the potential for large-scale fabrication for hydrogen separation applications." @default.
- W2775476645 created "2017-12-22" @default.
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- W2775476645 date "2018-03-01" @default.
- W2775476645 modified "2023-10-04" @default.
- W2775476645 title "The enhanced hydrogen separation performance of mixed matrix membranes by incorporation of two-dimensional ZIF-L into polyimide containing hydroxyl group" @default.
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- W2775476645 doi "https://doi.org/10.1016/j.memsci.2017.12.022" @default.
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