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- W2775490561 endingPage "129" @default.
- W2775490561 startingPage "126" @default.
- W2775490561 abstract "Three-component reaction of methyl α,α-disubstituted α-isocyanoacetates, primary amines, and aryl(vinyl) halides in the presence of Pd(OAc)2 (0.05 equiv) and Cu2O (1.0 equiv) provided 2,3,5,5-tetrasubstituted imidazolones via the formation of three chemical bonds. A copper-mediated migratory insertion of the isocyano group into the N–H bond of the amine followed by lactamization and Pd-catalyzed cross-coupling of the in situ generated amidinyl copper species with aryl(vinyl) halides accounted for the reaction outcome." @default.
- W2775490561 created "2017-12-22" @default.
- W2775490561 creator A5046225712 @default.
- W2775490561 creator A5070424085 @default.
- W2775490561 creator A5078512343 @default.
- W2775490561 date "2017-12-13" @default.
- W2775490561 modified "2023-10-03" @default.
- W2775490561 title "Cooperative Pd/Cu Catalysis: Multicomponent Synthesis of Tetrasubstituted Imidazolones from Methyl α-Isocyanoacetates, Primary Amines, and Aryl(vinyl) Iodides" @default.
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- W2775490561 doi "https://doi.org/10.1021/acs.orglett.7b03479" @default.
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- W2775490561 hasPublicationYear "2017" @default.
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