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• W2775676426 endingPage "1336" @default.
• W2775676426 startingPage "1332" @default.
• W2775676426 abstract "Abstract The synthesis and characterisation is presented of the compounds [An(Tren DMBS ){Pn(SiMe 3 ) 2 }] and [An(Tren TIPS ){Pn(SiMe 3 ) 2 }] [Tren DMBS =N(CH 2 CH 2 NSiMe 2 Bu t ) 3 , An=U, Pn=P, As, Sb, Bi; An=Th, Pn=P, As; Tren TIPS =N(CH 2 CH 2 NSiPr i 3 ) 3 , An=U, Pn=P, As, Sb; An=Th, Pn=P, As, Sb]. The U−Sb and Th−Sb moieties are unprecedented examples of any kind of An−Sb molecular bond, and the U−Bi bond is the first two‐centre‐two‐electron (2c–2e) one. The Th−Bi combination was too unstable to isolate, underscoring the fragility of these linkages. However, the U−Bi complex is the heaviest 2c–2e pairing of two elements involving an actinide on a macroscopic scale under ambient conditions, and this is exceeded only by An−An pairings prepared under cryogenic matrix isolation conditions. Thermolysis and photolysis experiments suggest that the U−Pn bonds degrade by homolytic bond cleavage, whereas the more redox‐robust thorium compounds engage in an acid–base/dehydrocoupling route." @default.
• W2775676426 created "2017-12-22" @default.
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• W2775676426 date "2017-12-29" @default.
• W2775676426 modified "2023-10-12" @default.
• W2775676426 title "Actinide–Pnictide (An−Pn) Bonds Spanning Non‐Metal, Metalloid, and Metal Combinations (An=U, Th; Pn=P, As, Sb, Bi)" @default.
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• W2775676426 doi "https://doi.org/10.1002/anie.201711824" @default.
• W2775676426 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/5814731" @default.
• W2775676426 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/29232498" @default.
• W2775676426 hasPublicationYear "2017" @default.
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