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- W2775733078 abstract "Palladium-catalyzed borylation of aryl sulfonium salts with bis(pinacolato)diboron has been achieved. Because of the sufficient reactivity of aryl sulfoniums and less catalyst-poisonous property of the leaving dialkyl sulfides, the present borylation proceeded under mild reaction conditions. Various functional groups, such as formyl, acetyl, cyano, nitro, and hydroxy groups, were well-tolerated. Aryl sulfoniums were easily prepared from the corresponding aryl sulfides and methyl triflate, and aryl sulfides could be transformed to the corresponding arylboronate esters in one-pot manners. The methylation selectively activated poorer leaving alkylsulfanyl units to culminate in selective borylation over chloro, tosyloxy, and better leaving arylsulfanyl and trifluoromethylsulfanyl units." @default.
- W2775733078 created "2017-12-22" @default.
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- W2775733078 date "2017-12-14" @default.
- W2775733078 modified "2023-10-18" @default.
- W2775733078 title "Palladium-Catalyzed Borylation of Aryl Sulfoniums with Diborons" @default.
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- W2775733078 doi "https://doi.org/10.1021/acscatal.7b03841" @default.
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