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- W2775794022 endingPage "925" @default.
- W2775794022 startingPage "920" @default.
- W2775794022 abstract "A protocol for the C–H activation/iodination of benzoic acids catalyzed by a simple iridium complex has been developed. The method described in this paper allows the ortho-selective iodination of a variety of benzoic acids under extraordinarily mild conditions in the absence of any additive or base in 1,1,1,3,3,3-hexafluoroisopropanol as the solvent. The iridium catalyst used tolerates air and moisture, and selectively gives ortho-iodobenzoic acids with high conversions. Mechanistic investigations revealed that an Ir(III)/Ir(V) catalytic cycle operates, and that the unique properties of HFIP enables the C–H iodination using the carboxylic moiety as a directing group." @default.
- W2775794022 created "2017-12-22" @default.
- W2775794022 creator A5019776623 @default.
- W2775794022 creator A5022721963 @default.
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- W2775794022 creator A5071313670 @default.
- W2775794022 creator A5081666499 @default.
- W2775794022 creator A5091712777 @default.
- W2775794022 date "2018-01-04" @default.
- W2775794022 modified "2023-10-18" @default.
- W2775794022 title "Base- and Additive-Free Ir-Catalyzed <i>ortho</i>-Iodination of Benzoic Acids: Scope and Mechanistic Investigations" @default.
- W2775794022 cites W1471349162 @default.
- W2775794022 cites W1834057360 @default.
- W2775794022 cites W1925851526 @default.
- W2775794022 cites W1963768535 @default.
- W2775794022 cites W1969382408 @default.
- W2775794022 cites W1974175192 @default.
- W2775794022 cites W1976355127 @default.
- W2775794022 cites W1976900023 @default.
- W2775794022 cites W1980934047 @default.
- W2775794022 cites W1981390016 @default.
- W2775794022 cites W1981916864 @default.
- W2775794022 cites W1985070846 @default.
- W2775794022 cites W1985944692 @default.
- W2775794022 cites W1987207730 @default.
- W2775794022 cites W1999746868 @default.
- W2775794022 cites W2003450340 @default.
- W2775794022 cites W2010584571 @default.
- W2775794022 cites W2016755677 @default.
- W2775794022 cites W2019052777 @default.
- W2775794022 cites W2022926795 @default.
- W2775794022 cites W2024983608 @default.
- W2775794022 cites W2027774080 @default.
- W2775794022 cites W2028824397 @default.
- W2775794022 cites W2031889588 @default.
- W2775794022 cites W2037956719 @default.
- W2775794022 cites W2046781848 @default.
- W2775794022 cites W2050016268 @default.
- W2775794022 cites W2058317949 @default.
- W2775794022 cites W2060595882 @default.
- W2775794022 cites W2065970229 @default.
- W2775794022 cites W2067433167 @default.
- W2775794022 cites W2075514990 @default.
- W2775794022 cites W2078574568 @default.
- W2775794022 cites W2078864272 @default.
- W2775794022 cites W2090555080 @default.
- W2775794022 cites W2092328284 @default.
- W2775794022 cites W2093371352 @default.
- W2775794022 cites W2095522283 @default.
- W2775794022 cites W2102896892 @default.
- W2775794022 cites W2119691024 @default.
- W2775794022 cites W2119994978 @default.
- W2775794022 cites W2123366338 @default.
- W2775794022 cites W2125014016 @default.
- W2775794022 cites W2128969383 @default.
- W2775794022 cites W2134720566 @default.
- W2775794022 cites W2135208833 @default.
- W2775794022 cites W2138317997 @default.
- W2775794022 cites W2139815397 @default.
- W2775794022 cites W2141963830 @default.
- W2775794022 cites W2153685870 @default.
- W2775794022 cites W2157958334 @default.
- W2775794022 cites W2161680524 @default.
- W2775794022 cites W2164603114 @default.
- W2775794022 cites W2169106836 @default.
- W2775794022 cites W2218266460 @default.
- W2775794022 cites W2267311193 @default.
- W2775794022 cites W2290560498 @default.
- W2775794022 cites W2313171562 @default.
- W2775794022 cites W2317547671 @default.
- W2775794022 cites W2318708152 @default.
- W2775794022 cites W2322047931 @default.
- W2775794022 cites W2323556332 @default.
- W2775794022 cites W2333896339 @default.
- W2775794022 cites W2339051409 @default.
- W2775794022 cites W2340805156 @default.
- W2775794022 cites W2394875873 @default.
- W2775794022 cites W2396516312 @default.
- W2775794022 cites W2412772006 @default.
- W2775794022 cites W2442012526 @default.
- W2775794022 cites W2463222434 @default.
- W2775794022 cites W2491297661 @default.
- W2775794022 cites W2527681110 @default.
- W2775794022 cites W2529896803 @default.
- W2775794022 cites W2531231330 @default.
- W2775794022 cites W2536741838 @default.
- W2775794022 cites W2538331700 @default.
- W2775794022 cites W2543162626 @default.
- W2775794022 cites W2589642209 @default.
- W2775794022 cites W2610439241 @default.
- W2775794022 cites W2744510660 @default.
- W2775794022 cites W2952807175 @default.
- W2775794022 cites W4235935841 @default.
- W2775794022 cites W4243805010 @default.
- W2775794022 cites W4362231989 @default.
- W2775794022 doi "https://doi.org/10.1021/acscatal.7b02987" @default.
- W2775794022 hasPublicationYear "2018" @default.