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• W2775861700 startingPage "817" @default.
• W2775861700 abstract "Environmental barrier coatings (EBCs) have widely been employed as protective coatings for SiC-based ceramic matrix composites (CMC-SiCs) against combustion corrosion in advanced gas turbines. During service, a layer of oxides forms beneath EBCs, which plays key role in lifetime of coated CMC-SiC parts. In this study, the kinetics of thermally grown silica oxide (silica-TGO) were examined through rare earth disilicates coated CMC-SiC composites subjected to corrosion under 50%H2O-50%O2 gas flow environment. Results revealed that growth of silica-TGO followed parabolic behavior, indicating diffusion controlled process. Calculated growth rates and activation energies of silica-TGO suggested that oxygen ion was the main active oxidant involved at relatively low partial pressure of water vapor. Corrosion environments containing different H2O/O2 ratios were also investigated and the data indicated that water vapor was also involved in growth of silica-TGO. The role of EBCs in corrosion process was also analyzed and discussed." @default.
• W2775861700 created "2018-01-05" @default.
• W2775861700 creator A5022305111 @default.
• W2775861700 creator A5040454053 @default.
• W2775861700 date "2018-03-01" @default.
• W2775861700 modified "2023-10-14" @default.
• W2775861700 title "Formation and growth of silica layer beneath environmental barrier coatings under water-vapor environment" @default.
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• W2775861700 doi "https://doi.org/10.1016/j.jallcom.2017.12.297" @default.
• W2775861700 hasPublicationYear "2018" @default.
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