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- W2775962512 abstract "Abstract The mononuclear gold(II) halide complexes [AuCl 3 ] − and [AuBr 3 ] − are formed in the gas phase by collision‐induced homolytic splitting of the only Au−C bond in the monoalkylgold(III) precursors [CF 3 AuX 3 ] − . The geometries of the whole series of [AuX 3 ] − complexes (X=F, Cl, Br, I) have been calculated by DFT methods. It has also been found that the neutral AuX 2 molecules behave as unsaturated species, showing significant affinity for an additional X − ligand. Moreover, in the open‐shell [AuX 3 ] − anions, homolytic splitting of one of the Au−X bonds and formation of the lower‐valent [AuX 2 ] − anions is favored over non‐reducing halide dissociation. They should therefore be prone to disproportionation." @default.
- W2775962512 created "2018-01-05" @default.
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- W2775962512 date "2018-01-16" @default.
- W2775962512 modified "2023-10-17" @default.
- W2775962512 title "Gold(II) Trihalide Complexes from Organogold(III) Precursors" @default.
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- W2775962512 doi "https://doi.org/10.1002/chem.201705509" @default.
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- W2775962512 hasPublicationYear "2018" @default.
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