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- W2775994525 abstract "An investigation of the magnetic properties and structure of the rhombohedral Fe2O3-V2O3 system is described. Almost complete solid solution exists at 1000°C. The magnetic behavior up to a V2O3 content of 40 per cent resembles that of α-Fe2O3, a weak spontaneous moment appearing at the Néel temperature. Between 40 and 80 per cent V2O2, there is weak ferrimagnetism reaching a maximum value of about 0.2μb per formula unit at 65 per cent 2O3. Between 85 and 100 per cent V2O3, the properties resemble those of V2O3. A neutron diffraction study shows that the hematite magnetic structure exists up to 60 per cent V2O3 but that at 70 per cent V2O3, the order is more short-range in nature. The transition from long-range to short-range order is apparently quite continuous. This is discussed with reference to the idea of direct V3+-V3+ interactions as advanced by Goodenough.(1) The weak ferrimagnetism is attributed to cation order of ilmenite type, similar to that observed in the Fe2O3-FeTiO3 system,(2) but present only to a small degree in Fe2O3-V2O3." @default.
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- W2775994525 date "1962-07-01" @default.
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- W2775994525 title "A magnetic and neutron diffraction study of the Fe2O3-V2O3 system∗" @default.
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- W2775994525 doi "https://doi.org/10.1016/0022-3697(62)90143-9" @default.
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