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- W2776220851 abstract "High-temperature fluidized-bed coating on alumina balls of 300-μm was carried out to produce particles covered with Ni-calcium hydroxyapatite (Ni-HAp) catalyst layer for partial oxidation of methane. The attrition durability of the catalyst-coated particles was investigated by a cold-model fluidization method. The catalytic partial oxidation of methane (POM) was demonstrated at 1073K in a fluidized bed reactor, where the catalyst-coated particles were fluidized by the reactant gas mixture. The effect of Ni loading (2.5wt.％ and 12.4wt.％ of the catalyst layer), superficial gas velocity on the CH4 conversion and H2 yield was investigated. The results clarified that the coating efficiency was improved by decreasing the superficial gas velocity. The catalyst particles produced in the present work had fair attrition durability, showing 5wt％ loss of catalyst layer after 48h fluidization at 0.60m/s. The CH4 conversion increased with decreasing superficial gas velocity, reaching more than 95％ at 0.18m/s irrespective of Ni loading of Ni-HAp catalyst used in the present work. An optimum superficial gas velocity was found, at which the CO selectivity and the H2 selectivity were both high." @default.
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- W2776220851 date "2009-01-01" @default.
- W2776220851 modified "2023-09-25" @default.
- W2776220851 title "Fluidized bed synthesis of particles covered with catalyst layer for partial oxidation of methane" @default.
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- W2776220851 doi "https://doi.org/10.14356/hptf.07110" @default.
- W2776220851 hasPublicationYear "2009" @default.
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