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- W2776314897 abstract "Abstract We describe a selective aerobic oxidation of meta‐biaryl phenols that enables rapid access to functionalized phenanthrenes. Aerobic oxidations attract interest due to their efficiency, but remain underutilized in complex molecule settings due to challenges of selectivity. We discuss these issues in the context of Cu catalysis, and highlight the advantages of confining oxygen activation and substrate oxidation to the catalyst's inner‐coordination sphere. This gives rise to predictable selectivity that we use for a concise synthesis of the aporphine dehydronornuciferine." @default.
- W2776314897 created "2018-01-05" @default.
- W2776314897 creator A5000924197 @default.
- W2776314897 creator A5058300825 @default.
- W2776314897 date "2018-01-16" @default.
- W2776314897 modified "2023-10-16" @default.
- W2776314897 title "Selectivity in the Aerobic Dearomatization of Phenols: Total Synthesis of Dehydronornuciferine by Chemo- and Regioselective Oxidation" @default.
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- W2776314897 doi "https://doi.org/10.1002/anie.201710271" @default.
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