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- W2776957107 abstract "In this work, five ruthenium complexes [Ru(p-cymene)LCl] containing phenolate-oxazoline ligands [L = 2-(4,5-dihydrooxazol-2-yl)phenol (1); L = 2-(4-methyl-4,5-dihydrooxazol-2-yl)phenol (2); L = 2-(4-ethyl-4,5-dihydrooxazol-2-yl)phenol (3); L = 2-(4-phenyl-4,5-dihydrooxazol-2-yl)phenol (4); and 2-(4,4-dimethyl-4,5-dihydrooxazol-2-yl)phenol (5)] were synthesized and characterized. The solid-state structures of all ruthenium complexes were determined by single-crystal X-ray diffraction. The catalytic activities of these complexes in the transfer hydrogenation reaction of nitroarene to aniline were investigated. Aniline and their derivatives were obtained in good to excellent yields with isopropanol as the hydride source. The present protocol provides an environmentally benign synthetic method for the reduction of nitroarenes to anilines without employing harsh reaction conditions. Theoretical studies employing density functional theory were carried with the aim to propose a feasible reaction mechanism and to..." @default.
- W2776957107 created "2018-01-05" @default.
- W2776957107 creator A5017996948 @default.
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- W2776957107 creator A5031969511 @default.
- W2776957107 creator A5082052299 @default.
- W2776957107 creator A5087848528 @default.
- W2776957107 date "2017-12-19" @default.
- W2776957107 modified "2023-09-24" @default.
- W2776957107 title "Half-Sandwich Ruthenium Phenolate–Oxazoline Complexes: Experimental and Theoretical Studies in Catalytic Transfer Hydrogenation of Nitroarene" @default.
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