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- W2777211674 abstract "Hollow inorganic nanostructures are important due to their applications in energy storage and conversion, catalysis, gas sensing, and biomedicine. Li 3 PO 4 is used as an isomerization catalyst for propylene oxide to selectively give allyl alcohol. We used a facile template-free method to synthesize hollow Li 3 PO 4 nanoparticles with size range of 500[Formula: see text]nm to 1500[Formula: see text]nm. The effect of concentration, agitation, ripening temperature and the ratio of starting reagents on the hollowing process is investigated. The most important factor to influence the hollowness was found to be the ratio of lithium ion to phosphate ion; as the ratio increases, the hollowness of the particles increases. When this ratio reached 3, the hollow nanostructures become dominant. As an isomerization catalyst for propylene oxide, 4-Li 3 PO 4 exhibited the highest conversion and best selectivity of allyl alcohol. The hydroxide ion of the precursor is adsorbed on the surface of the Li 3 PO 4 particles which results in different surface basicity." @default.
- W2777211674 created "2018-01-05" @default.
- W2777211674 creator A5051680690 @default.
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- W2777211674 date "2018-01-01" @default.
- W2777211674 modified "2023-09-24" @default.
- W2777211674 title "Facile Fabrication of Hollow Li3PO4 Catalyst via Ostwald Ripening" @default.
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- W2777211674 doi "https://doi.org/10.1142/s1793292018500042" @default.
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