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- W2778134386 abstract "Obtaining cognate single-heteroatom doping is highly desirable but least feasible in the research of nanoclusters (NCs). In this work, we reported a new Au16Ag1(S-Adm)13 NC, which is synthesized by the combination of single-atom engineering and ligand-exchange strategies. This new NC is so far the smallest crystallographically characterized Au-based NC protected by thiolate. The Au16Ag1(S-Adm)13 exhibited a tristratified Au3–Au2Ag1–Au1 kernel capped by staple-like motifs including one dimer and two tetramers. In stark contrast to the size-growth from Au18(S–C6H11)14 to Au21(S-Adm)15 via just the ligand-exchange method, combining single Ag doping on Au18(S–C6H11)14 resulted in the size-decrease from Au17Ag1(S–C6H11)14 to Au16Ag1(S-Adm)13. DFT calculations were performed to both homogold Au18 and single-heteroatom-doped Au17Ag1 to explain the opposite results under the same ligand-exchange reaction. Our work is expected to inspire the synthesis of new cognate single-atom-doped NCs by combining single-atom engineering and ligand-exchange strategies and also shed light on extensive understanding of the metal synergism effect in the NC range." @default.
- W2778134386 created "2018-01-05" @default.
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- W2778134386 date "2017-12-20" @default.
- W2778134386 modified "2023-10-15" @default.
- W2778134386 title "Combining the Single-Atom Engineering and Ligand-Exchange Strategies: Obtaining the Single-Heteroatom-Doped Au<sub>16</sub>Ag<sub>1</sub>(S-Adm)<sub>13</sub> Nanocluster with Atomically Precise Structure" @default.
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- W2778134386 doi "https://doi.org/10.1021/acs.inorgchem.7b02568" @default.
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