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• W2779378182 abstract "Photochemical and enzymatic production of methanol from CO2 was investigated with the system formate (FDH), aldehyde (AldDH) and alcohol (ADH) dehydrogenases, and methylviologen (MV2+) photoreduction by the visible light photosensitization of organo-photocatalyst, water-soluble porphyrin, tetraphenylporphyrin tetrasulfonate (H2TPPS) in the presence of triethanolamine (TEOA) as an electron donating reagent. To improve the methanol production from CO2, the kinetic parameters for methanol production with ADH and dithionite-reduced MV2+ were clarified. When the sample solution consisting of H2TPPS (100 μM), MV2+ (2.0 mM), TEOA (0.3 M), FDH (2.0 μM), AldDH (2.0 μM) and ADH (2.0 μM) in CO2 saturated 50 mM sodium pyrophosphate buffer was irradiated, continuous methanol production from CO2 was observed and methanol concentration produced was estimated to be 6.8 μM after 100 min irradiation." @default.
• W2779378182 created "2018-01-05" @default.
• W2779378182 creator A5045960919 @default.
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• W2779378182 date "2018-06-01" @default.
• W2779378182 modified "2023-10-01" @default.
• W2779378182 title "Methanol production from CO2 with the hybrid system of biocatalyst and organo-photocatalyst" @default.
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• W2779378182 doi "https://doi.org/10.1016/j.cattod.2017.12.029" @default.
• W2779378182 hasPublicationYear "2018" @default.
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