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- W2779436992 abstract "Electrochemical experiments are generally source of thermodynamic and kinetic data, analytical results or mechanistic considerations. The present contribution shows that using redox probes and the way of interpretation typical for molecules with multiple redox centers, electrochemistry can offer also information about the actual shape, geometry and rigidity of the studied molecules in the solution, and, consequently, about the electron distribution and delocalization. This “stereoelectrochemical” approach has been demonstrated on the large series of differently substituted oligonitro calix[4]arenes and thia calixarenes and represents an additional tool for better understanding of the relationship between structure and general properties of new compounds including supramolecules." @default.
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- W2779436992 date "2018-03-01" @default.
- W2779436992 modified "2023-10-16" @default.
- W2779436992 title "Stereoelectrochemistry of calixarenes – Molecules with multiple redox centers" @default.
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- W2779436992 doi "https://doi.org/10.1016/j.coelec.2017.12.006" @default.
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