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- W2780088985 abstract "Abstract Tunable supramolecular assembly has found various applications in biomedicine, molecular catalysis, optoelectronics, and nanofabrication. Unlike traditional covalent conjugation, non‐covalent introduction of a photoswitchable moiety enables reversible photomodulation of non‐photosensitive dipeptide supramolecular assembly. Under light illumination, a long‐lived photoacid generator releases a proton and mediates the dissociation of dipeptide‐based organogel, thereby resulting in sol formation. Under darkness, the photoswitchable moiety entraps a proton, resulting in gel regeneration. Furthermore, accompanying the isothermal recycled gel–sol transition in a spatially controlled manner, renewable patterns are spontaneously fabricated. This new concept of light‐controlled phase transition of amino acid‐based supramolecular assemblies will open up the possibility of wide applications." @default.
- W2780088985 created "2018-01-05" @default.
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- W2780088985 date "2018-01-16" @default.
- W2780088985 modified "2023-10-13" @default.
- W2780088985 title "A Photoinduced Reversible Phase Transition in a Dipeptide Supramolecular Assembly" @default.
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- W2780088985 doi "https://doi.org/10.1002/anie.201711547" @default.
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