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• W2780471821 endingPage "1801" @default.
• W2780471821 startingPage "1797" @default.
• W2780471821 abstract "Mn4+ -doped fluoride phosphors have been widely used in wide-gamut backlighting devices because of their extremely narrow emission band. Solid solutions of Na2 (Six Ge1-x )F6 :Mn4+ and Na2 (Gey Ti1-y )F6 :Mn4+ were successfully synthesized to elucidate the behavior of the zero-phonon line (ZPL) in different structures. The ratio between ZPL and the highest emission intensity υ6 phonon sideband exhibits a strong relationship with luminescent decay rate. First-principles calculations are conducted to model the variation in the structural and electronic properties of the prepared solid solutions as a function of the composition. To compensate for the limitations of the Rietveld refinement, electron paramagnetic resonance and high-resolution steady-state emission spectra are used to confirm the diverse local environment for Mn4+ in the structure. Finally, the spectral luminous efficacy of radiation (LER) is used to reveal the important role of ZPL in practical applications." @default.
• W2780471821 created "2018-01-05" @default.
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• W2780471821 date "2018-01-17" @default.
• W2780471821 modified "2023-10-17" @default.
• W2780471821 title "Control of Luminescence by Tuning of Crystal Symmetry and Local Structure in Mn⁴⁺ -Activated Narrow Band Fluoride Phosphors" @default.
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• W2780471821 doi "https://doi.org/10.1002/anie.201708814" @default.
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• W2780471821 hasPublicationYear "2018" @default.
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