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• W2780493844 abstract "Methane was directly converted to butene liquid fuel by microwave-induced non-oxidative catalytic dehydrogenation under 0.1–0.2 MPa. The results show that, under microwave heating in a two-stage fixed-bed reactor, in which nickel powder and NiO x –MoO y /SiO 2 are used as the catalyst, the methane–hydrogen mixture is used as the raw material, with no acetylene detected. The methane conversion is more than 73.2%, and the selectivity of methane to butene is 99.0%. Increasing the hydrogen/methane feed volume ratio increases methane conversion and selectivity. Gas chromatography/electron impact ionization/mass spectrometry chromatographic analysis showed that the liquid fuel produced by methane dehydrogenation oligomerization contained 89.44% of butene, and the rest was acetic acid, ethanol, butenol and butyric acid, and the content was 1.0–3.0 wt%." @default.
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• W2780493844 date "2017-12-01" @default.
• W2780493844 modified "2023-10-01" @default.
• W2780493844 title "Microwave-assisted direct synthesis of butene from high-selectivity methane" @default.
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• W2780493844 doi "https://doi.org/10.1098/rsos.171367" @default.
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