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• W2780596570 endingPage "97" @default.
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• W2780596570 abstract "ABSTRACT Ignition delay times of CH 3 NHCH 3 /O 2 /Ar mixtures are measured with a shock tube in the temperature range of 1040–1604 K. Different pressures (4, 8, and 18 atm) and equivalence ratios (0.5, 1, and 2) are investigated. A recently developed CH 3 NHCH 3 kinetic model is examined, and then modified by adding the hydrogen abstractions from CH 3 NHCH 3 by HO 2 and NO 2 . The rate constants of the hydrogen abstraction by HO 2 are estimated by analogy to the CH 3 OH + HO 2 system, and those of the hydrogen abstraction by NO 2 by analogy to the CH 3 NH 2 + HO 2 system. The modified model is well validated against the present measurements. Based on this model, sensitivity analysis and reaction pathway analysis are performed to provide insight into the chemical kinetics of CH 3 NHCH 3 ignition. CH 3 NHCH 3 is mainly consumed by hydrogen abstractions at low temperatures, and its unimolecular decomposition becomes important at higher temperatures." @default.
• W2780596570 created "2018-01-05" @default.
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• W2780596570 date "2017-12-20" @default.
• W2780596570 modified "2023-10-01" @default.
• W2780596570 title "Shock-Tube Experiments and Kinetic Modeling of CH₃NHCH₃Ignition at Elevated Pressures" @default.
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• W2780596570 doi "https://doi.org/10.1002/kin.21143" @default.
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