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- W2780821896 abstract "Abstract Thermodynamic quantities such as the isothermal compressibility, thermal expansion and the difference in the specific heat are calculated as a function of pressure (T = 10 K) for the α , α - and α ' phases of oxygen using the observed Raman frequencies of the two librons and one vibron from the literature through the mode Gruneisen parameter for this molecular solid. Calculated thermodynamic quantities decrease with increasing pressure with some discrepancies due to the different pressure – induced Raman frequency shifts of these modes studied for the α , α - and α ' phases of O 2 . A linear variation of the difference in the specific heat with the thermal expansion and also a linear variation of the thermal expansion with the isothermal compressibility (Pippard relations) are obtained for the α , α - and α ' phases of oxygen as studied here. Calculated isothermal compressibility, thermal expansion and the difference in the specific heat with the Pippard relations which we obtained here at various pressures (T = 10 K), can be examined with the experimental measurements for the α , α - and α ' phases of oxygen molecule." @default.
- W2780821896 created "2018-01-05" @default.
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- W2780821896 date "2018-04-01" @default.
- W2780821896 modified "2023-09-27" @default.
- W2780821896 title "Calculation of the thermodynamic quantities from the Raman frequency shifts and the Pippard relations for the α, α- and α' phases of oxygen" @default.
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- W2780821896 doi "https://doi.org/10.1016/j.ijleo.2017.12.086" @default.
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