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- W2781736202 abstract "Three-dimensional open porous graphitic carbon nitride with cyano groups (3D OPG-C3N4-CN) has been fabricated by a facile two-step process that combines NaCl-assisted freeze-drying with calcination. NaCl not only works as a template for the 3D open porous structure, but also facilitates the decomposition of g-C3N4 around 500 °C to some extent. Meanwhile, a moderate amount of cyano groups acting as electron capture centers are introduced at the edge of the 3D open porous g-C3N4 during the formation process. Compared with bulk g-C3N4 without NaCl assistance, the 3D OPG-C3N4-CN exhibits improved light absorption, reduced carrier recombination and more active sites. As a result, the enhanced hydrogen production of 3D OPG-C3N4-CN reaches up to 1590 μmol h-1 g-1 when using Pt as a cocatalyst, which is about six times as much as that of the bulk g-C3N4." @default.
- W2781736202 created "2018-01-12" @default.
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- W2781736202 date "2018-01-01" @default.
- W2781736202 modified "2023-10-14" @default.
- W2781736202 title "Salt-assisted synthesis of 3D open porous g-C<sub>3</sub>N<sub>4</sub> decorated with cyano groups for photocatalytic hydrogen evolution" @default.
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- W2781736202 doi "https://doi.org/10.1039/c7nr05927b" @default.
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