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- W2781848400 abstract "The influence of methyl pentanoate (MP) addition to n-heptane on the species pool in a nonpremixed counterflow flame fueled with n-heptane at atmospheric pressure has been investigated experimentally and numerically. Two non-premixed flames in counterflow configuration have been examined: (1) n-heptane/Ar (5.3%/94.7%) vs O2/Ar (24.1%/75.9%) and (2) n-heptane/MP/Ar (2.5%/2.5%/95%) vs O2/Ar (19.6%/80.4%). Both flames had similar strain rates and stoichiometric mixture fractions to allow an adequate comparison of their structures. The mole fraction profiles of the reactants, major products, and intermediates in both flames were measured using flame sampling molecular beam mass spectrometry. These experimental data were used for validation of a detailed chemical kinetic mechanism, which was proposed earlier for prediction of combustion characteristics of n-heptane/iso-octane/toluene/MP mixtures. The addition of MP to n-heptane reduced the flame temperature and the peak mole fractions of many flame intermediat..." @default.
- W2781848400 created "2018-01-12" @default.
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- W2781848400 date "2018-01-26" @default.
- W2781848400 modified "2023-09-26" @default.
- W2781848400 title "The Effect of Methyl Pentanoate Addition on the Structure of a Non-Premixed Counterflow <i>n</i>-Heptane/O<sub>2</sub> Flame" @default.
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- W2781848400 doi "https://doi.org/10.1021/acs.energyfuels.7b03185" @default.
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