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• W2782066347 startingPage "1328" @default.
• W2782066347 abstract "We synthesized copolymers consisting mostly of physically stable rigid polyimide (PI) and a low content of highly permeable rubbery polydimethylsiloxane (PDMS), that were crosslinked by CO2-philic ionic piperazinium groups attached to the side chains of the copolymers. These crosslinked copolymers (xPI-PDMSs) were fashioned into membranes that showed very high levels of thermochemical stability and excellent CO2 separation performance (PCO2 of 799 Barrer and CO2/N2 permselectivity of 15.7). The inclusion of the piperazinium groups not only endowed these xPI-PDMS membranes with increased selectivity for CO2, but also good resistance to CO2 plasticization. The effect of PDMS content on morphology and CO2 separation properties of xPI-PDMS was also investigated." @default.
• W2782066347 created "2018-01-12" @default.
• W2782066347 creator A5010305619 @default.
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• W2782066347 date "2018-01-01" @default.
• W2782066347 modified "2023-10-06" @default.
• W2782066347 title "Piperazinium-mediated crosslinked polyimide-polydimethylsiloxane (PI-PDMS) copolymer membranes: the effect of PDMS content on CO₂ separation" @default.
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• W2782066347 doi "https://doi.org/10.1039/c7ra10949k" @default.
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