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• W2782156959 abstract "Abstract Controlling triple phase boundary (TPB), an intersection of the ionic conductor, electronic conductor and gas phase as a major reaction site, is a key to improve cell performances for low-temperature solid oxide fuel cells. We report a synthesis of morphologically well-defined Gd0.1Ce0.9O1.95 (GDC) embedded Ba0.5Sr0.5Co0.8Fe0.2O3-δ (BSCF) nanofibers and their electrochemical performances as a cathode. Electrospun fibers prepared with a polymeric solution that contains crystalline Ba0.5Sr0.5Co0.8Fe0.2O3-δ particles in ∼200 nm size and Gd(NO3)3/Ce(NO3)3 precursors in an optimized weight ratio of 3 to 2 result in one dimensional structure without severe agglomeration and morphological collapse even after a high calcination at 1000 °C. As-prepared nanofibers have fast electron pathways along the axial direction of fibers, a higher surface area of 7.5 m2 g−1, and more oxygen reaction sites at TPBs than those of GDC/BSCF composite particles and core-shell nanofibers. As a result, the Gd0.1Ce0.9O1.95 embedded Ba0.5Sr0.5Co0.8Fe0.2O3-δ nanofiber cell shows excellent performances of the maximum power density of 0.65 W cm−2 at 550 °C and 1.02 W cm−2 at 600 °C, respectively." @default.
• W2782156959 created "2018-01-12" @default.
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• W2782156959 date "2018-02-01" @default.
• W2782156959 modified "2023-10-10" @default.
• W2782156959 title "Morphologically well-defined Gd0.1Ce0.9O1.95 embedded Ba0.5Sr0.5Co0.8Fe0.2O3-δ nanofiber with an enhanced triple phase boundary as cathode for low-temperature solid oxide fuel cells" @default.
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• W2782156959 doi "https://doi.org/10.1016/j.jpowsour.2017.12.065" @default.
• W2782156959 hasPublicationYear "2018" @default.
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