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- W2782632012 endingPage "439" @default.
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- W2782632012 abstract "Abstract Our novel synthetic route to isoellipticine featured palladium‐catalyzed intramolecular reactions for the construction of the B ring of the pyridocarbazole nucleus. The adequate palladium‐catalyzed reaction depended upon the oxidation conditions that were applied in order to prepare the immediate synthetic precursor. When CAN was used to make the quinone intermediate, an oxidative cyclization through a double C−H bond activation was applied. Conversely, when the oxidation condition involved TCCA as oxidant, a direct C−H arylation was employed. Both approaches showed similar efficiencies in order to construct the pyridocarbazole nucleus. Isoellipticine was prepared in only 5 steps with a 21%–23% overall yield." @default.
- W2782632012 created "2018-01-26" @default.
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- W2782632012 date "2018-01-09" @default.
- W2782632012 modified "2023-10-02" @default.
- W2782632012 title "Straightforward Synthesis of Isoellipticine by Palladium-Catalysed Coupling Reactions" @default.
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- W2782632012 doi "https://doi.org/10.1002/slct.201702602" @default.
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