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• W2782912341 abstract "Carbon is demonstrated as a mild and transition metal free catalyst for the preparation of N-rich heterocyclic compounds for the first time. The surface > C=O groups on nanodiamonds were identified as an active site, which most probably generates imidogene as a reactive species that triggers the reaction. The experimental results supported with density functional theory calculations were used to reveal a new reaction pathway, different from the conventional homogeneous one that indicates involvement of nitrogen radicals in the reaction." @default.
• W2782912341 created "2018-01-26" @default.
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• W2782912341 date "2018-04-01" @default.
• W2782912341 modified "2023-10-17" @default.
• W2782912341 title "Carbocatalysing the preparation of N-Rich heterocycles with an unprecedented mechanism" @default.
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• W2782912341 doi "https://doi.org/10.1016/j.carbon.2018.01.045" @default.
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