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- W2783007793 abstract "The electrostatic interaction between two non-identical, moderately charged colloids situated in close proximity of each other at a fluid interface is studied. By resorting to a well-justified model system, this problem is analytically solved within the framework of linearized Poisson-Boltzmann (PB) density functional theory (DFT). The resulting interaction comprises a surface and a line part, both of which, as functions of the inter-particle separation, show a rich behavior including monotonic as well as non-monotonic variations. In almost all cases, these variations cannot be captured correctly by using the superposition approximation. Moreover, expressions for the surface tensions, the line tensions and the fluid-fluid interfacial tension, which are all independent of the inter-particle separation, are obtained. Our results are expected to be particularly useful for emulsions stabilized by oppositely charged particles." @default.
- W2783007793 created "2018-01-26" @default.
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- W2783007793 date "2018-04-24" @default.
- W2783007793 modified "2023-09-25" @default.
- W2783007793 title "Electrostatic interaction between dissimilar colloids at fluid interfaces" @default.
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- W2783007793 doi "https://doi.org/10.1103/physreve.97.042611" @default.
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