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• W2783048360 endingPage "17" @default.
• W2783048360 startingPage "9" @default.
• W2783048360 abstract "Nanosized spinel Li4Ti5O12 was successfully synthesized by a solid state reaction method at 800°C according to the Li 4 Ti 5 O 12 cubic spinel phase structure. In this synthesizing process, anatase TiO 2 and Li 2 CO 3 were used as reactants. The average grain size of the synthesized powders was around 200 nm. The synthesized Li 4 Ti 5 O 12 powder was characterized X-ray Diffraction (XRD), X-ray Photoelectron Spectroscopy (XPS), Scanning Electron Microscopy (SEM), Energy Dispersive X-ray spectrometry (EDS), and Specific Surface Area Analyzer (BET, Brunner-Emmett-Teller) respectively. X-ray diffraction results show that calcination temperature and time have the important effects on the crystal structure of Li 4 Ti 5 O 12 powder. In this study, we used a first principle method, based on the density functional theory to explore electronic and structural properties of Li 4 Ti 5 O 12 , as anode material for lithium ion batteries. Differences on these properties between delithiation state Li 4 Ti 5 O 12 and lithiation state Li 7 Ti 5 O 12 are compared. All the predicted structural and electrochemical properties agree closely with the experimental findings in literature. The average intercalation voltage of 1.4V during charging/discharging were obtained. We have shown that the Li 4 Ti 5 O 12 material exhibits insulating behavior with the band gap of 3.16 and 3.90 eV using the GGA and GGA+U+J 0 calculations respectively. Li 7 Ti 5 O 12 becomes metallic as Li atoms inserted in Li 4 Ti 5 O 12 material. Spinel Li 4 Ti 5 O 12 has been regarded as an attractive anode material for the development of high-power lithium-ion batteries because of its unique attributes of high safety and rate capability." @default.
• W2783048360 created "2018-01-26" @default.
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• W2783048360 date "2018-01-01" @default.
• W2783048360 modified "2023-10-16" @default.
• W2783048360 title "Synthesis, Structure and Electronic Properties of Li₄Ti₅O₁₂ Anode Material for Lithium Ion Batteries" @default.
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• W2783048360 doi "https://doi.org/10.4028/www.scientific.net/ssp.271.9" @default.
• W2783048360 hasPublicationYear "2018" @default.
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