Matches in SemOpenAlex for { <https://semopenalex.org/work/W2783112704> ?p ?o ?g. }
- W2783112704 endingPage "3033" @default.
- W2783112704 startingPage "3023" @default.
- W2783112704 abstract "The desire for maximally efficient transformations in complex molecule synthesis has contributed to a surge of interest in C–H functionalization methods development in recent years. In contrast to the steady stream of methodological reports, however, there are noticeably fewer studies comparing the efficacies of different C–H functionalization protocols on a single structurally intricate substrate. Recognizing the importance of heteroatom incorporation in complex molecule synthesis, this report discloses a comparative examination of diverse strategies for C–O, C–N, and C–X bond formation through late-stage C–H oxidation of the tricyclic cyanthiwigin natural product core. Methods for allylic C–H acetoxylation, tertiary C–H hydroxylation, tertiary C–H amination, tertiary C–H azidation, and secondary C–H halogenation are explored. These efforts highlight the robustness and selectivities of many well-established protocols for C–H oxidation when applied to a complex molecular framework, and the findings are relevant to chemists aiming to employ such strategies in the context of chemical synthesis." @default.
- W2783112704 created "2018-01-26" @default.
- W2783112704 creator A5004644684 @default.
- W2783112704 creator A5014576358 @default.
- W2783112704 creator A5055333572 @default.
- W2783112704 creator A5062170356 @default.
- W2783112704 creator A5064849339 @default.
- W2783112704 date "2018-01-09" @default.
- W2783112704 modified "2023-09-28" @default.
- W2783112704 title "Cyanthiwigin Natural Product Core as a Complex Molecular Scaffold for Comparative Late-Stage C–H Functionalization Studies" @default.
- W2783112704 cites W1604247823 @default.
- W2783112704 cites W1956858148 @default.
- W2783112704 cites W1964622031 @default.
- W2783112704 cites W1964658576 @default.
- W2783112704 cites W1967812346 @default.
- W2783112704 cites W1974552222 @default.
- W2783112704 cites W1977678964 @default.
- W2783112704 cites W1984232099 @default.
- W2783112704 cites W1989688131 @default.
- W2783112704 cites W1993793186 @default.
- W2783112704 cites W2002149043 @default.
- W2783112704 cites W2014094450 @default.
- W2783112704 cites W2015674702 @default.
- W2783112704 cites W2017033936 @default.
- W2783112704 cites W2033817758 @default.
- W2783112704 cites W2035757873 @default.
- W2783112704 cites W2048118807 @default.
- W2783112704 cites W2049186688 @default.
- W2783112704 cites W2054802587 @default.
- W2783112704 cites W2056760113 @default.
- W2783112704 cites W2060296131 @default.
- W2783112704 cites W2061383088 @default.
- W2783112704 cites W2066309940 @default.
- W2783112704 cites W2067120735 @default.
- W2783112704 cites W2072380392 @default.
- W2783112704 cites W2073090551 @default.
- W2783112704 cites W2076655264 @default.
- W2783112704 cites W2078182163 @default.
- W2783112704 cites W2079977169 @default.
- W2783112704 cites W2086592520 @default.
- W2783112704 cites W2089058416 @default.
- W2783112704 cites W2090560403 @default.
- W2783112704 cites W2093265335 @default.
- W2783112704 cites W2094680700 @default.
- W2783112704 cites W2099693699 @default.
- W2783112704 cites W2106522802 @default.
- W2783112704 cites W2112758391 @default.
- W2783112704 cites W2118360399 @default.
- W2783112704 cites W2121016236 @default.
- W2783112704 cites W2125699661 @default.
- W2783112704 cites W2126689856 @default.
- W2783112704 cites W2146459733 @default.
- W2783112704 cites W2153484069 @default.
- W2783112704 cites W2156037101 @default.
- W2783112704 cites W2159402077 @default.
- W2783112704 cites W2164189430 @default.
- W2783112704 cites W2167602528 @default.
- W2783112704 cites W2170261800 @default.
- W2783112704 cites W2273062608 @default.
- W2783112704 cites W2280632944 @default.
- W2783112704 cites W2294312508 @default.
- W2783112704 cites W2317020669 @default.
- W2783112704 cites W2318230067 @default.
- W2783112704 cites W2320742306 @default.
- W2783112704 cites W2325684037 @default.
- W2783112704 cites W2334068183 @default.
- W2783112704 cites W2340195186 @default.
- W2783112704 cites W2395847103 @default.
- W2783112704 cites W2470325395 @default.
- W2783112704 cites W2529157935 @default.
- W2783112704 cites W2533747717 @default.
- W2783112704 cites W2585310671 @default.
- W2783112704 cites W2607259319 @default.
- W2783112704 cites W2624370041 @default.
- W2783112704 cites W2949873697 @default.
- W2783112704 cites W2951164032 @default.
- W2783112704 cites W579107163 @default.
- W2783112704 doi "https://doi.org/10.1021/acs.joc.7b03291" @default.
- W2783112704 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/29313681" @default.
- W2783112704 hasPublicationYear "2018" @default.
- W2783112704 type Work @default.
- W2783112704 sameAs 2783112704 @default.
- W2783112704 citedByCount "19" @default.
- W2783112704 countsByYear W27831127042018 @default.
- W2783112704 countsByYear W27831127042019 @default.
- W2783112704 countsByYear W27831127042020 @default.
- W2783112704 countsByYear W27831127042021 @default.
- W2783112704 countsByYear W27831127042022 @default.
- W2783112704 countsByYear W27831127042023 @default.
- W2783112704 crossrefType "journal-article" @default.
- W2783112704 hasAuthorship W2783112704A5004644684 @default.
- W2783112704 hasAuthorship W2783112704A5014576358 @default.
- W2783112704 hasAuthorship W2783112704A5055333572 @default.
- W2783112704 hasAuthorship W2783112704A5062170356 @default.
- W2783112704 hasAuthorship W2783112704A5064849339 @default.
- W2783112704 hasBestOaLocation W27831127041 @default.
- W2783112704 hasConcept C115537861 @default.
- W2783112704 hasConcept C120095180 @default.