Matches in SemOpenAlex for { <https://semopenalex.org/work/W2783126021> ?p ?o ?g. }
Showing items 1 to 65 of
65
with 100 items per page.
- W2783126021 abstract "This thesis concerns the direct synthesis of H2O2 from H2 and O2 which is then utilised in oxidation reactions. The direct synthesis of H2O2 provides a potentially moreenvironmentally-friendly approach than the widely employed anthraqunione process.This work aims to design catalysts that are capable of producing H2O2 via the direct synthesis route, then utilising the produced H2O2 in oxidation reactions.The first part of this thesis concerns the oxidation of phenol using H2O2 generated in situ from H2 and O2 in a one-pot process. Phenol was chosen as the model compoundto represent organic contamination in wastewater. H2O2 is a desirable oxidant for application in wastewater treatment owing to its high active oxygen content and the fact that it produces only water as a by-product of its decomposition. A palladium and iron containing catalyst was found to be an effective catalyst for completing thisreaction. Additionally, the occurrence and cause of leaching was extensively studied.The second part of this thesis concerns the oxidation of glycerol using H2O2 generated in situ from H2 and O2 in a one-pot process. Glycerol is a highly-functionalisedmaterial that can be used as a platform molecule for a variety of value-added products.Glycerol is currently produced as a by-product of biodiesel production, therefore there is considerable interest into its transformation into higher value products. Palladiumand iron containing catalysts were found to also be effective for completing this reaction. The effectiveness of in situ formed H2O2 and the bulk addition ofcommercial H2O2 was compared and highlighted the benefit of performing the reaction using in situ generated H2O2." @default.
- W2783126021 created "2018-01-26" @default.
- W2783126021 creator A5036202285 @default.
- W2783126021 date "2017-01-01" @default.
- W2783126021 modified "2023-09-23" @default.
- W2783126021 title "The in situ generation of H2O2 from H2 and O2 for use in oxidation reactions" @default.
- W2783126021 hasPublicationYear "2017" @default.
- W2783126021 type Work @default.
- W2783126021 sameAs 2783126021 @default.
- W2783126021 citedByCount "0" @default.
- W2783126021 crossrefType "dissertation" @default.
- W2783126021 hasAuthorship W2783126021A5036202285 @default.
- W2783126021 hasConcept C127413603 @default.
- W2783126021 hasConcept C159390177 @default.
- W2783126021 hasConcept C159750122 @default.
- W2783126021 hasConcept C161790260 @default.
- W2783126021 hasConcept C178790620 @default.
- W2783126021 hasConcept C185592680 @default.
- W2783126021 hasConcept C192562407 @default.
- W2783126021 hasConcept C2777702071 @default.
- W2783126021 hasConcept C39432304 @default.
- W2783126021 hasConcept C42360764 @default.
- W2783126021 hasConcept C502130503 @default.
- W2783126021 hasConcept C55904794 @default.
- W2783126021 hasConcept C90982505 @default.
- W2783126021 hasConceptScore W2783126021C127413603 @default.
- W2783126021 hasConceptScore W2783126021C159390177 @default.
- W2783126021 hasConceptScore W2783126021C159750122 @default.
- W2783126021 hasConceptScore W2783126021C161790260 @default.
- W2783126021 hasConceptScore W2783126021C178790620 @default.
- W2783126021 hasConceptScore W2783126021C185592680 @default.
- W2783126021 hasConceptScore W2783126021C192562407 @default.
- W2783126021 hasConceptScore W2783126021C2777702071 @default.
- W2783126021 hasConceptScore W2783126021C39432304 @default.
- W2783126021 hasConceptScore W2783126021C42360764 @default.
- W2783126021 hasConceptScore W2783126021C502130503 @default.
- W2783126021 hasConceptScore W2783126021C55904794 @default.
- W2783126021 hasConceptScore W2783126021C90982505 @default.
- W2783126021 hasLocation W27831260211 @default.
- W2783126021 hasOpenAccess W2783126021 @default.
- W2783126021 hasPrimaryLocation W27831260211 @default.
- W2783126021 hasRelatedWork W1537940700 @default.
- W2783126021 hasRelatedWork W1561258045 @default.
- W2783126021 hasRelatedWork W1807283640 @default.
- W2783126021 hasRelatedWork W2031876079 @default.
- W2783126021 hasRelatedWork W2037820794 @default.
- W2783126021 hasRelatedWork W2071632181 @default.
- W2783126021 hasRelatedWork W2107956028 @default.
- W2783126021 hasRelatedWork W2346568746 @default.
- W2783126021 hasRelatedWork W2461113111 @default.
- W2783126021 hasRelatedWork W2516935834 @default.
- W2783126021 hasRelatedWork W2539342232 @default.
- W2783126021 hasRelatedWork W2899893780 @default.
- W2783126021 hasRelatedWork W2921969562 @default.
- W2783126021 hasRelatedWork W3196182494 @default.
- W2783126021 hasRelatedWork W2837896060 @default.
- W2783126021 hasRelatedWork W2861398312 @default.
- W2783126021 hasRelatedWork W2868565991 @default.
- W2783126021 hasRelatedWork W2881878081 @default.
- W2783126021 hasRelatedWork W2941136317 @default.
- W2783126021 hasRelatedWork W2956701516 @default.
- W2783126021 isParatext "false" @default.
- W2783126021 isRetracted "false" @default.
- W2783126021 magId "2783126021" @default.
- W2783126021 workType "dissertation" @default.