Matches in SemOpenAlex for { <https://semopenalex.org/work/W2783143476> ?p ?o ?g. }
- W2783143476 endingPage "6635" @default.
- W2783143476 startingPage "6625" @default.
- W2783143476 abstract "Abstract. Chloromethane (CH3Cl) is an important provider of chlorine to the stratosphere but detailed knowledge of its budget is missing. Stable isotope analysis is a potentially powerful tool to constrain CH3Cl flux estimates. The largest degree of isotope fractionation is expected to occur for deuterium in CH3Cl in the hydrogen abstraction reactions with its main sink reactant tropospheric OH and its minor sink reactant Cl atoms. We determined the isotope fractionation by stable hydrogen isotope analysis of the fraction of CH3Cl remaining after reaction with hydroxyl and chlorine radicals in a 3.5 m3 Teflon smog chamber at 293 ± 1 K. We measured the stable hydrogen isotope values of the unreacted CH3Cl using compound-specific thermal conversion isotope ratio mass spectrometry. The isotope fractionations of CH3Cl for the reactions with hydroxyl and chlorine radicals were found to be -264±45 and -280±11 ‰, respectively. For comparison, we performed similar experiments using methane (CH4) as the target compound with OH and obtained a fractionation constant of -205±6 ‰ which is in good agreement with values previously reported. The observed large kinetic isotope effects are helpful when employing isotopic analyses of CH3Cl in the atmosphere to improve our knowledge of its atmospheric budget." @default.
- W2783143476 created "2018-01-26" @default.
- W2783143476 creator A5011498252 @default.
- W2783143476 creator A5018658312 @default.
- W2783143476 creator A5023410401 @default.
- W2783143476 creator A5034627757 @default.
- W2783143476 creator A5053541072 @default.
- W2783143476 creator A5054257434 @default.
- W2783143476 date "2018-05-09" @default.
- W2783143476 modified "2023-10-14" @default.
- W2783143476 title "Mass spectrometric measurement of hydrogen isotope fractionation for the reactions of chloromethane with OH and Cl" @default.
- W2783143476 cites W1485278182 @default.
- W2783143476 cites W1585609718 @default.
- W2783143476 cites W1800611761 @default.
- W2783143476 cites W1932465400 @default.
- W2783143476 cites W1952060907 @default.
- W2783143476 cites W1968564773 @default.
- W2783143476 cites W1971745688 @default.
- W2783143476 cites W1972902864 @default.
- W2783143476 cites W1974629656 @default.
- W2783143476 cites W1979588446 @default.
- W2783143476 cites W1980312426 @default.
- W2783143476 cites W1980736058 @default.
- W2783143476 cites W1991688600 @default.
- W2783143476 cites W2001175988 @default.
- W2783143476 cites W2013932933 @default.
- W2783143476 cites W2015565958 @default.
- W2783143476 cites W2016902215 @default.
- W2783143476 cites W2024184661 @default.
- W2783143476 cites W2030778948 @default.
- W2783143476 cites W2035695506 @default.
- W2783143476 cites W2039256779 @default.
- W2783143476 cites W2044746360 @default.
- W2783143476 cites W2048714905 @default.
- W2783143476 cites W2058058616 @default.
- W2783143476 cites W2059977454 @default.
- W2783143476 cites W2060228787 @default.
- W2783143476 cites W2061410615 @default.
- W2783143476 cites W2067121399 @default.
- W2783143476 cites W2075637452 @default.
- W2783143476 cites W2095715736 @default.
- W2783143476 cites W2099719945 @default.
- W2783143476 cites W2100362187 @default.
- W2783143476 cites W2113327787 @default.
- W2783143476 cites W2121358891 @default.
- W2783143476 cites W2126622049 @default.
- W2783143476 cites W2137423981 @default.
- W2783143476 cites W2153816112 @default.
- W2783143476 cites W2168960627 @default.
- W2783143476 cites W2171976453 @default.
- W2783143476 cites W2556487889 @default.
- W2783143476 cites W2564645089 @default.
- W2783143476 cites W2732758066 @default.
- W2783143476 cites W2791047223 @default.
- W2783143476 cites W2802281438 @default.
- W2783143476 cites W4300580526 @default.
- W2783143476 doi "https://doi.org/10.5194/acp-18-6625-2018" @default.
- W2783143476 hasPublicationYear "2018" @default.
- W2783143476 type Work @default.
- W2783143476 sameAs 2783143476 @default.
- W2783143476 citedByCount "6" @default.
- W2783143476 countsByYear W27831434762019 @default.
- W2783143476 countsByYear W27831434762020 @default.
- W2783143476 countsByYear W27831434762021 @default.
- W2783143476 countsByYear W27831434762023 @default.
- W2783143476 crossrefType "journal-article" @default.
- W2783143476 hasAuthorship W2783143476A5011498252 @default.
- W2783143476 hasAuthorship W2783143476A5018658312 @default.
- W2783143476 hasAuthorship W2783143476A5023410401 @default.
- W2783143476 hasAuthorship W2783143476A5034627757 @default.
- W2783143476 hasAuthorship W2783143476A5053541072 @default.
- W2783143476 hasAuthorship W2783143476A5054257434 @default.
- W2783143476 hasBestOaLocation W27831434761 @default.
- W2783143476 hasConcept C107872376 @default.
- W2783143476 hasConcept C111368507 @default.
- W2783143476 hasConcept C113196181 @default.
- W2783143476 hasConcept C121332964 @default.
- W2783143476 hasConcept C127313418 @default.
- W2783143476 hasConcept C139066938 @default.
- W2783143476 hasConcept C145269806 @default.
- W2783143476 hasConcept C161790260 @default.
- W2783143476 hasConcept C164304813 @default.
- W2783143476 hasConcept C178790620 @default.
- W2783143476 hasConcept C185592680 @default.
- W2783143476 hasConcept C195511166 @default.
- W2783143476 hasConcept C22117777 @default.
- W2783143476 hasConcept C2777428142 @default.
- W2783143476 hasConcept C2779334269 @default.
- W2783143476 hasConcept C30545975 @default.
- W2783143476 hasConcept C505241676 @default.
- W2783143476 hasConcept C512968161 @default.
- W2783143476 hasConcept C51813073 @default.
- W2783143476 hasConcept C58364064 @default.
- W2783143476 hasConcept C62520636 @default.
- W2783143476 hasConcept C69928629 @default.
- W2783143476 hasConcept C97428945 @default.
- W2783143476 hasConceptScore W2783143476C107872376 @default.
- W2783143476 hasConceptScore W2783143476C111368507 @default.