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- W2783160130 endingPage "969" @default.
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- W2783160130 abstract "Long-alkyl tail triphenylene (TP) side-chain liquid crystalline polymers (SCLCPs) with different spacer length (P-m-TP, m = 2, 3, 4, 6, 8, which is the number of carbon atom in the flexible alkyl spacers) have been successfully synthesized via free radical polymerization. The differential scanning calorimetry (DSC), polarized light microscopy (POM), ultraviolet-visible spectroscopy (UV-Vis), wide-angle X-ray diffraction (WAXD) and small-angle X-ray scattering (SAXS) measurements were performed to investigate the influence of multiple effects on the self-organization behaviors of P-m-TP, including steric effect, decoupling effect and π-π stacking effect. The experimental results revealed that P-m-TP (m = 2, 3, 4) formed the columnar phase which was developed by the TP moieties and the main chain as a whole, suggesting that the side-chains had strong steric effect even though the number of spacer length (m) exceeded 4. In addition, the clearing points (Tis) of the polymers were above 300 °C. When m = 6 and 8, the polymers displayed hexagonal columnar phase and exhibited the low Tis (91 and 80 °C respectively), originating from the self-assembly of triphenylene due to the decoupling effect and π-π stacking effect. This work offers a viable and inspiring pathway to control the phase transition temperature and phase structure of TP SCLCPs via simply tailoring the spacer length and increasing the alkyl tail length of TP." @default.
- W2783160130 created "2018-01-26" @default.
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- W2783160130 date "2018-03-06" @default.
- W2783160130 modified "2023-10-12" @default.
- W2783160130 title "Multiple Effects Tailoring the Self-organization Behaviors of Triphenylene Side-chain Liquid Crystalline Polymers via Changing the Spacer Length" @default.
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- W2783160130 doi "https://doi.org/10.1007/s10118-018-2108-9" @default.
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