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- W2783163822 abstract "Abstract Metallic phase molybdenum disulfide (MoS 2 ) is well known for orders of magnitude higher conductivity than 2H semiconducting phase MoS 2 . Herein, for the first time, the authors design and fabricate a novel porous nanotube assembled with vertically aligned metallic MoS 2 nanosheets by using the scalable solvothermal method. This metallic nanotube has the following advantages: (i) intrinsic high electrical conductivity that promotes the rate performance of battery and eliminates the using of conductive additive; (ii) hierarchical, hollow, porous, and aligned structure that assists the electrolyte transportation and diffusion; (iii) tubular structure that avoids restacking of 2D nanosheets, and therefore maintains the electrochemistry cycling stability; and (iv) a shortened ion diffusion path, that improves the rate performance. This 1D metallic MoS 2 nanotube is demonstrated to be a promising anode material for lithium‐ion batteries. The unique structure delivers an excellent reversible capacity of 1100 mA h g −1 under a current density of 5 A g −1 after 350 cycles, and an outstanding rate performance of 589 mA h g −1 at a current density of 20 A g −1 . Furthermore, attributed to the material's metallic properties, the electrode comprising 100% pure material without any additive provides an ideal system for the fundamental electrochemical study of metallic MoS 2 . This study first reveals the characteristic anodic peak at 1.5 V in cyclic voltammetry of metallic MoS 2. This research sheds light on the fabrication of metallic 1D, 2D, or even 3D structures with 2D nanosheets as building blocks for various applications." @default.
- W2783163822 created "2018-01-26" @default.
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- W2783163822 date "2018-01-12" @default.
- W2783163822 modified "2023-10-15" @default.
- W2783163822 title "Ion Transport Nanotube Assembled with Vertically Aligned Metallic MoS<sub>2</sub> for High Rate Lithium‐Ion Batteries" @default.
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- W2783163822 doi "https://doi.org/10.1002/aenm.201702779" @default.
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