FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2783172225> ?p ?o ?g. }

• W2783172225 endingPage "1613" @default.
• W2783172225 startingPage "1604" @default.
• W2783172225 abstract "A study of neptunium (Np) chemistry in the complex oxo-selenium system has been performed. Hereby, two sets of precipitation experiments were conducted, investigating the influence of the initial oxidation state of selenium using SeIVO2 and H2SeVIO4 with NpV in alkali nitrate solution, keeping the ratio of Np/Se constant. Surprising results were observed. Five novel neptunium and selenium bearing compounds have been obtained by slow evaporation from aqueous solution. The novel NpIV phase K4-x[Np(SeO3)4-x(HSeO3)x]·(H2O)1.5 (1) crystallizes in green-colored, plate-shaped crystals and was obtained by adding SeO2 and ANO3 to a NpV stock solution. Single-crystal X-ray diffraction reveals one-dimensional chain structures composed of square antiprismatic NpO8 polyhedra linked via four trigonal pyramidal SeO3 and HSeO3 units. Raman spectral analysis supports the presence of both selenite and hydroselenite due to the presence of corresponding modes within the spectra. The addition of selenic acid to a NpV stock solution resulted in the precipitation of elongated rose prisms of K2[(NpO2)2(SeO4)3(H2O)2]·(H2O)1.5 (2), Rb2[(NpO2)2(SeO4)3(H2O)2]·(H2O)2 (3) and K9[(NpO2)9(SeO4)13.5(H2O)6]·(H2O)12 (4) as well as light red plates of Cs2[(NpO2)2(SeO4)3] (5). To our knowledge, this is the first report of NpVI selenates. All four structures show two-dimensional layered structures with alkali cations acting as charge balancing counter cations. Hereby the layers of compounds 2 and 3 are found to be orientational geometric isomers. Distinctly different phenomena are made responsible for the phase formation within these systems. The kinetically driven process of NpV disproportionation led to the formation of the NpIV selenites in the SeIV-based system, whereas the oxidation of NpV by reduction of nitrate in acidic conditions is responsible for the formation of the NpVI selenates in the SeVI system. The influence of air oxygen is also discussed for the latter reaction." @default.
• W2783172225 created "2018-01-26" @default.
• W2783172225 creator A5015805986 @default.
• W2783172225 creator A5048976924 @default.
• W2783172225 creator A5056366336 @default.
• W2783172225 creator A5060148383 @default.
• W2783172225 creator A5069665652 @default.
• W2783172225 date "2018-01-22" @default.
• W2783172225 modified "2023-09-25" @default.
• W2783172225 title "Unexpected Behavior of Np in Oxo-selenate/Oxo-selenite Systems" @default.
• W2783172225 cites W1489454430 @default.
• W2783172225 cites W1596401142 @default.
• W2783172225 cites W1969360633 @default.
• W2783172225 cites W1969736096 @default.
• W2783172225 cites W1971202897 @default.
• W2783172225 cites W1981230636 @default.
• W2783172225 cites W1985893512 @default.
• W2783172225 cites W1988062912 @default.
• W2783172225 cites W1990170643 @default.
• W2783172225 cites W1992936556 @default.
• W2783172225 cites W1993853796 @default.
• W2783172225 cites W2002510565 @default.
• W2783172225 cites W2007482718 @default.
• W2783172225 cites W2023305387 @default.
• W2783172225 cites W2053176918 @default.
• W2783172225 cites W2073969854 @default.
• W2783172225 cites W2081601277 @default.
• W2783172225 cites W2085260464 @default.
• W2783172225 cites W2094247182 @default.
• W2783172225 cites W2101741054 @default.
• W2783172225 cites W2106527814 @default.
• W2783172225 cites W2112723500 @default.
• W2783172225 cites W2138797405 @default.
• W2783172225 cites W2142684841 @default.
• W2783172225 cites W2144574024 @default.
• W2783172225 cites W2171102997 @default.
• W2783172225 cites W2313462268 @default.
• W2783172225 cites W2325795972 @default.
• W2783172225 cites W2558810050 @default.
• W2783172225 cites W2607211649 @default.
• W2783172225 cites W2949165566 @default.
• W2783172225 cites W2949248880 @default.
• W2783172225 cites W2949687930 @default.
• W2783172225 cites W2950227893 @default.
• W2783172225 cites W2950337548 @default.
• W2783172225 cites W2950503230 @default.
• W2783172225 cites W2950530576 @default.
• W2783172225 cites W2950961884 @default.
• W2783172225 cites W2951141848 @default.
• W2783172225 cites W2951875279 @default.
• W2783172225 cites W2952060867 @default.
• W2783172225 cites W2952128579 @default.
• W2783172225 cites W2952398229 @default.
• W2783172225 cites W2952930930 @default.
• W2783172225 cites W3119109183 @default.
• W2783172225 cites W352246361 @default.
• W2783172225 cites W4251195205 @default.
• W2783172225 cites W880270955 @default.
• W2783172225 doi "https://doi.org/10.1021/acs.inorgchem.7b02961" @default.
• W2783172225 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/29355311" @default.
• W2783172225 hasPublicationYear "2018" @default.
• W2783172225 type Work @default.
• W2783172225 sameAs 2783172225 @default.
• W2783172225 citedByCount "7" @default.
• W2783172225 countsByYear W27831722252019 @default.
• W2783172225 countsByYear W27831722252020 @default.
• W2783172225 countsByYear W27831722252021 @default.
• W2783172225 countsByYear W27831722252022 @default.
• W2783172225 crossrefType "journal-article" @default.
• W2783172225 hasAuthorship W2783172225A5015805986 @default.
• W2783172225 hasAuthorship W2783172225A5048976924 @default.
• W2783172225 hasAuthorship W2783172225A5056366336 @default.
• W2783172225 hasAuthorship W2783172225A5060148383 @default.
• W2783172225 hasAuthorship W2783172225A5069665652 @default.
• W2783172225 hasConcept C113196181 @default.
• W2783172225 hasConcept C120665830 @default.
• W2783172225 hasConcept C121332964 @default.
• W2783172225 hasConcept C135788738 @default.
• W2783172225 hasConcept C147789679 @default.
• W2783172225 hasConcept C178790620 @default.
• W2783172225 hasConcept C179104552 @default.
• W2783172225 hasConcept C184651966 @default.
• W2783172225 hasConcept C185592680 @default.
• W2783172225 hasConcept C198091228 @default.
• W2783172225 hasConcept C2778591166 @default.
• W2783172225 hasConcept C2780347965 @default.
• W2783172225 hasConcept C40003534 @default.
• W2783172225 hasConcept C43617362 @default.
• W2783172225 hasConcept C516372188 @default.
• W2783172225 hasConcept C544153396 @default.
• W2783172225 hasConcept C553756173 @default.
• W2783172225 hasConcept C8010536 @default.
• W2783172225 hasConceptScore W2783172225C113196181 @default.
• W2783172225 hasConceptScore W2783172225C120665830 @default.
• W2783172225 hasConceptScore W2783172225C121332964 @default.
• W2783172225 hasConceptScore W2783172225C135788738 @default.
• W2783172225 hasConceptScore W2783172225C147789679 @default.
• W2783172225 hasConceptScore W2783172225C178790620 @default.

• next