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- W2783192801 abstract "Rotaxanes consisting of achiral axle and achiral ring components can possess supramolecular chirality due to their unique geometrical architectures. To synthesize such chiral rotaxanes, we adapted a prerotaxane method based on aminolysis of a metacyclophane type prerotaxane that had planar chirality, which is composed of an achiral stopper unit and a crown ether type ring component. The prerotaxanes were well resolved using chiral HPLC into a pair of enantiomerically pure prerotaxanes, which were transferred into corresponding chiral rotaxanes, respectively. Obtained chiral rotaxanes were revealed to have considerable enantioselectivity." @default.
- W2783192801 created "2018-01-26" @default.
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- W2783192801 date "2018-01-09" @default.
- W2783192801 modified "2023-09-30" @default.
- W2783192801 title "The Asymmetry is Derived from Mechanical Interlocking of Achiral Axle and Achiral Ring Components –Syntheses and Properties of Optically Pure [2]Rotaxanes–" @default.
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- W2783192801 doi "https://doi.org/10.3390/sym10010020" @default.
- W2783192801 hasPublicationYear "2018" @default.
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