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- W2783199861 abstract "The selenoether-functionalized imidazolium salt N-[(phenylseleno)methylene)]-N′-methylimidazolium chloride (LH+Cl–) was transformed into the metal–carbene complexes [AgCl(L)], [AuCl(L)], [PdCl2(L)], and [PtCl2(L)] by the reaction with Ag2O and an additional transmetalation reaction of [AgCl(L)] with [(THT)AuCl], [(COD)PdCl2], and [(COD)PtCl2], respectively (THT = tetrahydrothiophene, COD = cyclooctadiene). The compound [AuI2Cl(L)] was prepared by oxidation of [AuCl(L)] with elemental iodine. The microwave-assisted decomposition of [PdCl2(L)] in the ionic liquid 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([BMIm]NTf2) or in propylene carbonate led to the formation of Pd17Se15 nanoparticles of 51 ± 17 or 26 ± 7 nm diameter, respectively. The decomposition of the platinum complex resulted in either small Pt clusters around 1 nm size from the ionic liquid suspension or Pt nanoparticles of 3 ± 1 nm diameter in propylene carbonate. High-resolution X-ray photoelectron spectroscopy (HR-XPS) and 13C cross-polarization magic-angle spinning (CP MAS) NMR indicated that the surface of Pt clusters and crystalline Pt nanoparticles is formed by an amorphous Pt(II)/Se shell and by carbene ligand residues." @default.
- W2783199861 created "2018-01-26" @default.
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- W2783199861 date "2018-01-17" @default.
- W2783199861 modified "2023-10-16" @default.
- W2783199861 title "Silver, Gold, Palladium, and Platinum N-heterocyclic Carbene Complexes Containing a Selenoether-Functionalized Imidazol-2-ylidene Moiety" @default.
- W2783199861 cites W1575973410 @default.
- W2783199861 cites W1608037977 @default.
- W2783199861 cites W1813302654 @default.
- W2783199861 cites W1883779550 @default.
- W2783199861 cites W1899556128 @default.
- W2783199861 cites W1909685617 @default.
- W2783199861 cites W1965748938 @default.
- W2783199861 cites W1966910457 @default.
- W2783199861 cites W1967274063 @default.
- W2783199861 cites W1972197907 @default.
- W2783199861 cites W1978890358 @default.
- W2783199861 cites W1980528527 @default.
- W2783199861 cites W1983632513 @default.
- W2783199861 cites W1985908220 @default.
- W2783199861 cites W1993587675 @default.
- W2783199861 cites W1994220506 @default.
- W2783199861 cites W1994612762 @default.
- W2783199861 cites W1999535002 @default.
- W2783199861 cites W2003555872 @default.
- W2783199861 cites W2005308311 @default.
- W2783199861 cites W2007467770 @default.
- W2783199861 cites W2016865263 @default.
- W2783199861 cites W2024498209 @default.
- W2783199861 cites W2024995813 @default.
- W2783199861 cites W2028746804 @default.
- W2783199861 cites W2029586934 @default.
- W2783199861 cites W2029875475 @default.
- W2783199861 cites W2035528101 @default.
- W2783199861 cites W2041123784 @default.
- W2783199861 cites W2043400485 @default.
- W2783199861 cites W2046286719 @default.
- W2783199861 cites W2048139193 @default.
- W2783199861 cites W2053011214 @default.
- W2783199861 cites W2053383714 @default.
- W2783199861 cites W2056667683 @default.
- W2783199861 cites W2057329378 @default.
- W2783199861 cites W2057367191 @default.
- W2783199861 cites W2057689609 @default.
- W2783199861 cites W2060611033 @default.
- W2783199861 cites W2069734545 @default.
- W2783199861 cites W2083533045 @default.
- W2783199861 cites W2087266904 @default.
- W2783199861 cites W2099252084 @default.
- W2783199861 cites W2103443566 @default.
- W2783199861 cites W2104057453 @default.
- W2783199861 cites W2107724943 @default.
- W2783199861 cites W2118787685 @default.
- W2783199861 cites W2122232390 @default.
- W2783199861 cites W2129255762 @default.
- W2783199861 cites W2130941962 @default.
- W2783199861 cites W2131350133 @default.
- W2783199861 cites W2133142785 @default.
- W2783199861 cites W2141453896 @default.
- W2783199861 cites W2144640096 @default.
- W2783199861 cites W2149660454 @default.
- W2783199861 cites W2155546110 @default.
- W2783199861 cites W2167903144 @default.
- W2783199861 cites W2257885700 @default.
- W2783199861 cites W2276930415 @default.
- W2783199861 cites W2313503572 @default.
- W2783199861 cites W2316979660 @default.
- W2783199861 cites W2325339364 @default.
- W2783199861 cites W2327072228 @default.
- W2783199861 cites W2342243379 @default.
- W2783199861 cites W2436645641 @default.
- W2783199861 cites W2463722397 @default.
- W2783199861 cites W2472551131 @default.
- W2783199861 cites W2509333775 @default.
- W2783199861 cites W2546241933 @default.
- W2783199861 cites W2576760514 @default.
- W2783199861 cites W2596067820 @default.
- W2783199861 cites W2596323432 @default.
- W2783199861 cites W2606140310 @default.
- W2783199861 cites W2609724868 @default.
- W2783199861 cites W2626362425 @default.
- W2783199861 cites W2725495705 @default.
- W2783199861 cites W3100099893 @default.
- W2783199861 cites W4244645406 @default.
- W2783199861 cites W4252607070 @default.
- W2783199861 doi "https://doi.org/10.1021/acs.organomet.7b00678" @default.
- W2783199861 hasPublicationYear "2018" @default.
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