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• W2783201489 abstract "Abstract Searching for highly efficient bifunctional electrocatalysts for the oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) using nonnoble metal‐based catalysts is essential for the development of many energy conversion systems, including rechargeable fuel cells and metal–air batteries. Here, Co 9– x Fe x S 8 /Co,Fe‐N‐C hybrids wrapped by reduced graphene oxide (rGO) (abbreviated as S‐Co 9– x Fe x S 8 @rGO) are synthesized through a semivulcanization and calcination method using graphene oxide (GO) wrapped bimetallic zeolite imidazolate framework (ZIF) Co,Fe‐ZIF (CoFe‐ZIF@GO) as precursors. Benefiting from the synergistic effect of OER active CoFeS and ORR active Co,Fe‐N‐C in a single component, as well as high dispersity and enhanced conductivity derived from rGO coating and Fe‐doping, the obtained S‐Co 9– x Fe x S 8 @rGO‐10 catalyst shows an ultrasmall overpotential of ≈0.29 V at 10 mA cm −2 in OER and a half‐wave potential of 0.84 V in ORR, combining a superior oxygen electrode activity of ≈0.68 V in 0.1 m KOH." @default.
• W2783201489 created "2018-01-26" @default.
• W2783201489 creator A5010309536 @default.
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• W2783201489 creator A5061671556 @default.
• W2783201489 creator A5062213729 @default.
• W2783201489 date "2018-01-10" @default.
• W2783201489 modified "2023-10-17" @default.
• W2783201489 title "Reduced Graphene Oxide‐Wrapped Co_9–<i>_x</i>Fe<i>_x</i>S₈/Co,Fe‐N‐C Composite as Bifunctional Electrocatalyst for Oxygen Reduction and Evolution" @default.
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• W2783201489 doi "https://doi.org/10.1002/smll.201703748" @default.
• W2783201489 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/29318748" @default.
• W2783201489 hasPublicationYear "2018" @default.
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