FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2783223040> ?p ?o ?g. }

• W2783223040 endingPage "110" @default.
• W2783223040 startingPage "103" @default.
• W2783223040 abstract "The reduction of carbon dioxide to renewable fuels and feedstocks offers opportunities for large-scale, long-term energy storage. The synthesis of efficient CO2 reduction electrocatalysts with high C2:C1 selectivity remains a field of intense interest. Here we present electro-redeposition, the dissolution and redeposition of copper from a sol–gel, to enhance copper catalysts in terms of their morphology, oxidation state and consequent performance. We utilized in situ soft X-ray absorption spectroscopy to track the oxidation state of copper under CO2 reduction conditions with time resolution. The sol–gel material slows the electrochemical reduction of copper, enabling control over nanoscale morphology and the stabilization of Cu+ at negative potentials. CO2 reduction experiments, in situ X-ray spectroscopy and density functional theory simulations revealed the beneficial interplay between sharp morphologies and Cu+ oxidation state. The catalyst exhibits a partial ethylene current density of 160 mA cm–2 (−1.0 V versus reversible hydrogen electrode) and an ethylene/methane ratio of 200. Catalysts that can selectively reduce carbon dioxide to C2+ products are attractive for the generation of more complex and useful chemicals. Here, an electro-redeposited copper catalyst is shown to provide excellent selectivity and high current density for ethylene formation. Detailed characterization and theory link the performance to the catalyst morphology." @default.
• W2783223040 created "2018-01-26" @default.
• W2783223040 creator A5001195523 @default.
• W2783223040 creator A5010426030 @default.
• W2783223040 creator A5012487063 @default.
• W2783223040 creator A5023006306 @default.
• W2783223040 creator A5054680242 @default.
• W2783223040 creator A5056257017 @default.
• W2783223040 creator A5058414727 @default.
• W2783223040 creator A5071721558 @default.
• W2783223040 creator A5076284262 @default.
• W2783223040 creator A5077862151 @default.
• W2783223040 date "2018-01-15" @default.
• W2783223040 modified "2023-10-18" @default.
• W2783223040 title "Catalyst electro-redeposition controls morphology and oxidation state for selective carbon dioxide reduction" @default.
• W2783223040 cites W1931367894 @default.
• W2783223040 cites W1981626052 @default.
• W2783223040 cites W1985240449 @default.
• W2783223040 cites W1995765480 @default.
• W2783223040 cites W1996773402 @default.
• W2783223040 cites W1998300029 @default.
• W2783223040 cites W2001884976 @default.
• W2783223040 cites W2004857182 @default.
• W2783223040 cites W2014444172 @default.
• W2783223040 cites W2021478109 @default.
• W2783223040 cites W2032435170 @default.
• W2783223040 cites W2053036337 @default.
• W2783223040 cites W2058947355 @default.
• W2783223040 cites W2060023027 @default.
• W2783223040 cites W2060429741 @default.
• W2783223040 cites W2067027712 @default.
• W2783223040 cites W2070384700 @default.
• W2783223040 cites W2074964984 @default.
• W2783223040 cites W2080918368 @default.
• W2783223040 cites W2082498048 @default.
• W2783223040 cites W2121817924 @default.
• W2783223040 cites W2126396070 @default.
• W2783223040 cites W2132299680 @default.
• W2783223040 cites W2134707622 @default.
• W2783223040 cites W2144904466 @default.
• W2783223040 cites W2170456486 @default.
• W2783223040 cites W2199208506 @default.
• W2783223040 cites W2225958871 @default.
• W2783223040 cites W2302970633 @default.
• W2783223040 cites W2320849513 @default.
• W2783223040 cites W2331744161 @default.
• W2783223040 cites W2332681130 @default.
• W2783223040 cites W2336845479 @default.
• W2783223040 cites W2338294784 @default.
• W2783223040 cites W2470552650 @default.
• W2783223040 cites W2480341173 @default.
• W2783223040 cites W2493300873 @default.
• W2783223040 cites W2496132953 @default.
• W2783223040 cites W2511654019 @default.
• W2783223040 cites W2522135447 @default.
• W2783223040 cites W2522565392 @default.
• W2783223040 cites W2531688930 @default.
• W2783223040 cites W2531985189 @default.
• W2783223040 cites W2560832335 @default.
• W2783223040 cites W2565135807 @default.
• W2783223040 cites W2567342708 @default.
• W2783223040 cites W2569888948 @default.
• W2783223040 cites W2573313258 @default.
• W2783223040 cites W2586677999 @default.
• W2783223040 cites W2600150897 @default.
• W2783223040 cites W2608300873 @default.
• W2783223040 cites W2743443266 @default.
• W2783223040 cites W2749320269 @default.
• W2783223040 cites W2756857621 @default.
• W2783223040 cites W2765148856 @default.
• W2783223040 cites W2770867421 @default.
• W2783223040 cites W4232627022 @default.
• W2783223040 cites W4363610698 @default.
• W2783223040 doi "https://doi.org/10.1038/s41929-017-0018-9" @default.
• W2783223040 hasPublicationYear "2018" @default.
• W2783223040 type Work @default.
• W2783223040 sameAs 2783223040 @default.
• W2783223040 citedByCount "663" @default.
• W2783223040 countsByYear W27832230402018 @default.
• W2783223040 countsByYear W27832230402019 @default.
• W2783223040 countsByYear W27832230402020 @default.
• W2783223040 countsByYear W27832230402021 @default.
• W2783223040 countsByYear W27832230402022 @default.
• W2783223040 countsByYear W27832230402023 @default.
• W2783223040 crossrefType "journal-article" @default.
• W2783223040 hasAuthorship W2783223040A5001195523 @default.
• W2783223040 hasAuthorship W2783223040A5010426030 @default.
• W2783223040 hasAuthorship W2783223040A5012487063 @default.
• W2783223040 hasAuthorship W2783223040A5023006306 @default.
• W2783223040 hasAuthorship W2783223040A5054680242 @default.
• W2783223040 hasAuthorship W2783223040A5056257017 @default.
• W2783223040 hasAuthorship W2783223040A5058414727 @default.
• W2783223040 hasAuthorship W2783223040A5071721558 @default.
• W2783223040 hasAuthorship W2783223040A5076284262 @default.
• W2783223040 hasAuthorship W2783223040A5077862151 @default.
• W2783223040 hasBestOaLocation W27832230402 @default.
• W2783223040 hasConcept C104779481 @default.
• W2783223040 hasConcept C118792377 @default.

• next