Matches in SemOpenAlex for { <https://semopenalex.org/work/W2783271899> ?p ?o ?g. }
- W2783271899 endingPage "530" @default.
- W2783271899 startingPage "523" @default.
- W2783271899 abstract "The decay rate constants of benzhydrylium ions generated by laser irradiation in acetonitrile have been determined photometrically. The decay of the stable carbocation with an electron-releasing substituent was decelerated with addition of LiClO4, being attributed to the decrease of the recombination of the cations with the counter anions. On the contrary, the decay of the highly reactive carbocation was accelerated, indicating the occurrence of the reaction with perchlorate anion. The second-order rate constants (k2) for the reactions of benzhydrylium ions with methanol, ethanol, i-propanol, t-butanol, and water were determined in acetonitrile in the presence of 3 mM LiClO4 for benzhydrylium ions less electrophilic than 3,5-dimethyl-4′-chlorobenzhydrylium ion and in the absence of LiClO4 for the remaining reactive benzhydrylium ions. Their logarithms were linearly correlated with the electrophilicity parameters (E) in Mayr’s equation, log k2 = sN(E + N). Based on the correlations the nucleophilicity para..." @default.
- W2783271899 created "2018-01-26" @default.
- W2783271899 creator A5002234524 @default.
- W2783271899 creator A5011025752 @default.
- W2783271899 creator A5038332637 @default.
- W2783271899 creator A5054430260 @default.
- W2783271899 creator A5072459535 @default.
- W2783271899 date "2018-04-15" @default.
- W2783271899 modified "2023-10-18" @default.
- W2783271899 title "Nucleophilicities of Alcohols and Water in Acetonitrile Based on Reactivities of Benzhydrylium Ions" @default.
- W2783271899 cites W1532377613 @default.
- W2783271899 cites W1543529383 @default.
- W2783271899 cites W1565879982 @default.
- W2783271899 cites W1963787258 @default.
- W2783271899 cites W1964435530 @default.
- W2783271899 cites W1970474300 @default.
- W2783271899 cites W1971812208 @default.
- W2783271899 cites W1973255918 @default.
- W2783271899 cites W1978453629 @default.
- W2783271899 cites W1978481702 @default.
- W2783271899 cites W1991256825 @default.
- W2783271899 cites W1994773789 @default.
- W2783271899 cites W2011167881 @default.
- W2783271899 cites W2011529244 @default.
- W2783271899 cites W2020629227 @default.
- W2783271899 cites W2026916683 @default.
- W2783271899 cites W2033145782 @default.
- W2783271899 cites W2041726370 @default.
- W2783271899 cites W2044039308 @default.
- W2783271899 cites W2044955865 @default.
- W2783271899 cites W2052548880 @default.
- W2783271899 cites W2056040984 @default.
- W2783271899 cites W2057837113 @default.
- W2783271899 cites W2059824140 @default.
- W2783271899 cites W2069971072 @default.
- W2783271899 cites W2074540587 @default.
- W2783271899 cites W2075752884 @default.
- W2783271899 cites W2079165343 @default.
- W2783271899 cites W2079993883 @default.
- W2783271899 cites W2084305045 @default.
- W2783271899 cites W2111812652 @default.
- W2783271899 cites W2112935558 @default.
- W2783271899 cites W2120567479 @default.
- W2783271899 cites W2124235566 @default.
- W2783271899 cites W2132574712 @default.
- W2783271899 cites W2141705345 @default.
- W2783271899 cites W2314312817 @default.
- W2783271899 cites W2314365858 @default.
- W2783271899 cites W2315471309 @default.
- W2783271899 cites W2322902045 @default.
- W2783271899 cites W2326051534 @default.
- W2783271899 cites W2328501447 @default.
- W2783271899 cites W2329778651 @default.
- W2783271899 cites W2331241678 @default.
- W2783271899 cites W2332641971 @default.
- W2783271899 cites W2334355833 @default.
- W2783271899 cites W2336634611 @default.
- W2783271899 cites W2949207315 @default.
- W2783271899 cites W2949322926 @default.
- W2783271899 cites W2951711227 @default.
- W2783271899 cites W2953333466 @default.
- W2783271899 cites W4213196194 @default.
- W2783271899 cites W4232476250 @default.
- W2783271899 cites W4237566933 @default.
- W2783271899 cites W4239396415 @default.
- W2783271899 doi "https://doi.org/10.1246/bcsj.20170360" @default.
- W2783271899 hasPublicationYear "2018" @default.
- W2783271899 type Work @default.
- W2783271899 sameAs 2783271899 @default.
- W2783271899 citedByCount "3" @default.
- W2783271899 countsByYear W27832718992021 @default.
- W2783271899 countsByYear W27832718992023 @default.
- W2783271899 crossrefType "journal-article" @default.
- W2783271899 hasAuthorship W2783271899A5002234524 @default.
- W2783271899 hasAuthorship W2783271899A5011025752 @default.
- W2783271899 hasAuthorship W2783271899A5038332637 @default.
- W2783271899 hasAuthorship W2783271899A5054430260 @default.
- W2783271899 hasAuthorship W2783271899A5072459535 @default.
- W2783271899 hasConcept C145148216 @default.
- W2783271899 hasConcept C178790620 @default.
- W2783271899 hasConcept C185592680 @default.
- W2783271899 hasConcept C2777463227 @default.
- W2783271899 hasConcept C75473681 @default.
- W2783271899 hasConceptScore W2783271899C145148216 @default.
- W2783271899 hasConceptScore W2783271899C178790620 @default.
- W2783271899 hasConceptScore W2783271899C185592680 @default.
- W2783271899 hasConceptScore W2783271899C2777463227 @default.
- W2783271899 hasConceptScore W2783271899C75473681 @default.
- W2783271899 hasIssue "4" @default.
- W2783271899 hasLocation W27832718991 @default.
- W2783271899 hasOpenAccess W2783271899 @default.
- W2783271899 hasPrimaryLocation W27832718991 @default.
- W2783271899 hasRelatedWork W1987674700 @default.
- W2783271899 hasRelatedWork W2022476004 @default.
- W2783271899 hasRelatedWork W2030355543 @default.
- W2783271899 hasRelatedWork W2032352337 @default.
- W2783271899 hasRelatedWork W2046277083 @default.
- W2783271899 hasRelatedWork W2148654603 @default.