Matches in SemOpenAlex for { <https://semopenalex.org/work/W2783272088> ?p ?o ?g. }
- W2783272088 endingPage "3987" @default.
- W2783272088 startingPage "3981" @default.
- W2783272088 abstract "An efficient protocol was developed to construct functionally dense quaternary carbons with concomitant formation of a new Csp3–Csp3 bond via Pd-catalyzed decarboxylative transformation of vinyl cyclic carbonates. This redox-neutral catalytic system features stereocontrolled formation of multisubstituted allylic scaffolds with an aldehyde functionality generated in situ, and it typically can be performed at room temperature without any additives. DFT calculations provide a rationale toward the selective formation of these compounds and reveal a complex mechanism that with the help of microkinetic models is able to reproduce the nontrivial dependence of the identity of the product on the nature of the substituents in the substrate." @default.
- W2783272088 created "2018-01-26" @default.
- W2783272088 creator A5019047795 @default.
- W2783272088 creator A5021898713 @default.
- W2783272088 creator A5039612429 @default.
- W2783272088 creator A5065337367 @default.
- W2783272088 creator A5072616772 @default.
- W2783272088 date "2018-01-16" @default.
- W2783272088 modified "2023-10-14" @default.
- W2783272088 title "A Domino Process toward Functionally Dense Quaternary Carbons through Pd-Catalyzed Decarboxylative C(sp<sup>3</sup>)–C(sp<sup>3</sup>) Bond Formation" @default.
- W2783272088 cites W1899103796 @default.
- W2783272088 cites W1968143231 @default.
- W2783272088 cites W1976634798 @default.
- W2783272088 cites W1980972289 @default.
- W2783272088 cites W1983986309 @default.
- W2783272088 cites W1985699940 @default.
- W2783272088 cites W2006684341 @default.
- W2783272088 cites W2007814829 @default.
- W2783272088 cites W2009373560 @default.
- W2783272088 cites W2012413753 @default.
- W2783272088 cites W2013092331 @default.
- W2783272088 cites W2019100110 @default.
- W2783272088 cites W2023678939 @default.
- W2783272088 cites W2029402467 @default.
- W2783272088 cites W2036758375 @default.
- W2783272088 cites W2053014304 @default.
- W2783272088 cites W2055884298 @default.
- W2783272088 cites W2058810301 @default.
- W2783272088 cites W2079050104 @default.
- W2783272088 cites W2084113358 @default.
- W2783272088 cites W2085805998 @default.
- W2783272088 cites W2086606359 @default.
- W2783272088 cites W2096353395 @default.
- W2783272088 cites W2097129068 @default.
- W2783272088 cites W2098486174 @default.
- W2783272088 cites W2105634484 @default.
- W2783272088 cites W2115291312 @default.
- W2783272088 cites W2122383632 @default.
- W2783272088 cites W2137073195 @default.
- W2783272088 cites W2148764311 @default.
- W2783272088 cites W2148893042 @default.
- W2783272088 cites W2150493946 @default.
- W2783272088 cites W2162600945 @default.
- W2783272088 cites W2168025565 @default.
- W2783272088 cites W2233842751 @default.
- W2783272088 cites W2280197809 @default.
- W2783272088 cites W2283198005 @default.
- W2783272088 cites W2286931814 @default.
- W2783272088 cites W2308789388 @default.
- W2783272088 cites W2319738610 @default.
- W2783272088 cites W2328545533 @default.
- W2783272088 cites W2331502730 @default.
- W2783272088 cites W2339469480 @default.
- W2783272088 cites W2404853881 @default.
- W2783272088 cites W2413961131 @default.
- W2783272088 cites W2429369419 @default.
- W2783272088 cites W2512641233 @default.
- W2783272088 cites W2513976098 @default.
- W2783272088 cites W2518650848 @default.
- W2783272088 cites W2523991984 @default.
- W2783272088 cites W2533049456 @default.
- W2783272088 cites W2547325653 @default.
- W2783272088 cites W2554839371 @default.
- W2783272088 cites W2587301581 @default.
- W2783272088 cites W2592713455 @default.
- W2783272088 cites W2605326066 @default.
- W2783272088 cites W2661054184 @default.
- W2783272088 cites W2724134996 @default.
- W2783272088 cites W2737154143 @default.
- W2783272088 cites W2737643599 @default.
- W2783272088 cites W2761481263 @default.
- W2783272088 cites W2765986950 @default.
- W2783272088 cites W2766620454 @default.
- W2783272088 cites W2949971679 @default.
- W2783272088 cites W2950564504 @default.
- W2783272088 cites W2951826498 @default.
- W2783272088 cites W2953239288 @default.
- W2783272088 doi "https://doi.org/10.1021/jacs.7b12608" @default.
- W2783272088 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/29337542" @default.
- W2783272088 hasPublicationYear "2018" @default.
- W2783272088 type Work @default.
- W2783272088 sameAs 2783272088 @default.
- W2783272088 citedByCount "109" @default.
- W2783272088 countsByYear W27832720882018 @default.
- W2783272088 countsByYear W27832720882019 @default.
- W2783272088 countsByYear W27832720882020 @default.
- W2783272088 countsByYear W27832720882021 @default.
- W2783272088 countsByYear W27832720882022 @default.
- W2783272088 countsByYear W27832720882023 @default.
- W2783272088 crossrefType "journal-article" @default.
- W2783272088 hasAuthorship W2783272088A5019047795 @default.
- W2783272088 hasAuthorship W2783272088A5021898713 @default.
- W2783272088 hasAuthorship W2783272088A5039612429 @default.
- W2783272088 hasAuthorship W2783272088A5065337367 @default.
- W2783272088 hasAuthorship W2783272088A5072616772 @default.
- W2783272088 hasConcept C111368507 @default.
- W2783272088 hasConcept C120095180 @default.
- W2783272088 hasConcept C127313418 @default.