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• W2783283891 abstract "AbstractThree mononuclear nickel(II) and copper(II) complexes, [Ni(L)2(py)2] (1), [Ni(L)2(DMF)(H2O)] (2), and [Cu(L)2] (3), where HL = 2-((Z)-(4-methoxyphenylimino)methyl)-4,6-dichlorophenol, py = pyridine and DMF = N,N-dimethylformamide, have been synthesized and their structures determined by single crystal X-ray analysis. Complexes 1–3 crystallized in the monoclinic system of the space groups C2/c, P21/n, and P21/c, respectively. The crystal structures of 1 and 2 present an octahedral geometry at the metal center and 3 shows a square-planar geometry. The FT-IR spectra, UV–vis spectra, and magnetic susceptibility measurements agree with the observed crystal structures. EPR spectra indicate a dx2–y2 ground state (g|| > g⊥ > 2.0023 and A|| > A⊥) for 3 at RT and LNT. The results of simultaneous TG-DTA analyses of 1 and 3 showed the final degradation products are NiO for 1 and CuO for 3. The Schiff base (HL) behaves as monobasic bidentate ligand possessing N and O donor atoms. Electrochemical properties for..." @default.
• W2783283891 created "2018-01-26" @default.
• W2783283891 creator A5050013875 @default.
• W2783283891 creator A5054238631 @default.
• W2783283891 creator A5066643341 @default.
• W2783283891 date "2018-01-17" @default.
• W2783283891 modified "2023-10-14" @default.
• W2783283891 title "Syntheses, characterizations, crystal structures, antibacterial and SOD-like activities of nickel(II) and copper(II) complexes with 2-((Z)-(4-methoxyphenylimino)methyl)-4,6-dichlorophenol" @default.
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• W2783283891 doi "https://doi.org/10.1080/00958972.2018.1424839" @default.
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