FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2783297391> ?p ?o ?g. }

• W2783297391 endingPage "3647" @default.
• W2783297391 startingPage "3638" @default.
• W2783297391 abstract "The diffusion of alkaline chlorides (LiCl, KCl, and CsCl) and water in mesoporous silica samples with pore sizes covering the range from micropores (2 nm) up to mesopores larger than 30 nm have been measured by resorting to a simple diffusional technique in the case of electrolytes and 1H NMR in the case of water. The morphology of the silica samples varies from a microporous structure, an interconnected network of pores, and typical mesoporous materials with ink-bottle pores, with increasing pore size. The release of electrolytes from the silica as a function of time exhibits two differentiated regimes, at short and long times, which correlates quite well with the size of the pores and that of necks of the pores, respectively. The diffusion of water inside the pores follows the same trend with pore size that the diffusion of electrolytes, indicating a coupling between the ions and water diffusional mobilities. The tortuosity effect on the diffusion of all studied electrolytes and water shows a monotonic slight increase with decreasing diameter for pores larger than 5 nm, while the tortuosity factor increases markedly for smaller pores. In microporous and mesoporous silica with pore sizes below 10 nm, the tortuosity factor of Li+ ion is much larger than those for K+ and Cs+ ions, since its diffusion is hindered by a stronger electrostatic interaction with the ionizable silanol groups on the pore wall; and also larger than that for water diffusion which it is retarded by a weaker hydrogen bond interaction with the silanol groups. The differences in tortuosity factors among alkaline chlorides and water become negligible for pore sizes larger than 10 nm. The spin–lattice relaxation time measurements of 1H-water and Li+ ions confirm this behavior." @default.
• W2783297391 created "2018-01-26" @default.
• W2783297391 creator A5007189943 @default.
• W2783297391 creator A5071629336 @default.
• W2783297391 creator A5078139740 @default.
• W2783297391 creator A5079246360 @default.
• W2783297391 creator A5087463513 @default.
• W2783297391 creator A5088193361 @default.
• W2783297391 date "2018-02-05" @default.
• W2783297391 modified "2023-10-17" @default.
• W2783297391 title "Diffusion of Water and Electrolytes in Mesoporous Silica with a Wide Range of Pore Sizes" @default.
• W2783297391 cites W1968576210 @default.
• W2783297391 cites W1972660664 @default.
• W2783297391 cites W1976741620 @default.
• W2783297391 cites W1981596913 @default.
• W2783297391 cites W1985991166 @default.
• W2783297391 cites W1987330726 @default.
• W2783297391 cites W1992553670 @default.
• W2783297391 cites W1997630751 @default.
• W2783297391 cites W2002047929 @default.
• W2783297391 cites W2005860047 @default.
• W2783297391 cites W2006226701 @default.
• W2783297391 cites W2009200880 @default.
• W2783297391 cites W2009690554 @default.
• W2783297391 cites W2011895878 @default.
• W2783297391 cites W2015148937 @default.
• W2783297391 cites W2026986365 @default.
• W2783297391 cites W2027415939 @default.
• W2783297391 cites W2029087156 @default.
• W2783297391 cites W2032190810 @default.
• W2783297391 cites W2035003890 @default.
• W2783297391 cites W2035180242 @default.
• W2783297391 cites W2036963891 @default.
• W2783297391 cites W2053925698 @default.
• W2783297391 cites W2065316356 @default.
• W2783297391 cites W2066085728 @default.
• W2783297391 cites W2076283593 @default.
• W2783297391 cites W2082797746 @default.
• W2783297391 cites W2082853447 @default.
• W2783297391 cites W2086026323 @default.
• W2783297391 cites W2087978882 @default.
• W2783297391 cites W2091056667 @default.
• W2783297391 cites W2312199777 @default.
• W2783297391 cites W2319829599 @default.
• W2783297391 cites W2323882202 @default.
• W2783297391 cites W2513585299 @default.
• W2783297391 cites W2528483640 @default.
• W2783297391 cites W2531963788 @default.
• W2783297391 cites W255890309 @default.
• W2783297391 cites W2584605529 @default.
• W2783297391 cites W2595717915 @default.
• W2783297391 cites W2949556942 @default.
• W2783297391 cites W3103621808 @default.
• W2783297391 cites W4231425380 @default.
• W2783297391 cites W639844833 @default.
• W2783297391 cites W843007777 @default.
• W2783297391 doi "https://doi.org/10.1021/acs.jpcc.7b11555" @default.
• W2783297391 hasPublicationYear "2018" @default.
• W2783297391 type Work @default.
• W2783297391 sameAs 2783297391 @default.
• W2783297391 citedByCount "30" @default.
• W2783297391 countsByYear W27832973912018 @default.
• W2783297391 countsByYear W27832973912019 @default.
• W2783297391 countsByYear W27832973912020 @default.
• W2783297391 countsByYear W27832973912021 @default.
• W2783297391 countsByYear W27832973912022 @default.
• W2783297391 countsByYear W27832973912023 @default.
• W2783297391 crossrefType "journal-article" @default.
• W2783297391 hasAuthorship W2783297391A5007189943 @default.
• W2783297391 hasAuthorship W2783297391A5071629336 @default.
• W2783297391 hasAuthorship W2783297391A5078139740 @default.
• W2783297391 hasAuthorship W2783297391A5079246360 @default.
• W2783297391 hasAuthorship W2783297391A5087463513 @default.
• W2783297391 hasAuthorship W2783297391A5088193361 @default.
• W2783297391 hasConcept C121332964 @default.
• W2783297391 hasConcept C127413603 @default.
• W2783297391 hasConcept C147789679 @default.
• W2783297391 hasConcept C159985019 @default.
• W2783297391 hasConcept C161790260 @default.
• W2783297391 hasConcept C17525397 @default.
• W2783297391 hasConcept C178790620 @default.
• W2783297391 hasConcept C179104552 @default.
• W2783297391 hasConcept C185250623 @default.
• W2783297391 hasConcept C185592680 @default.
• W2783297391 hasConcept C192562407 @default.
• W2783297391 hasConcept C2777496208 @default.
• W2783297391 hasConcept C2777581007 @default.
• W2783297391 hasConcept C42360764 @default.
• W2783297391 hasConcept C6648577 @default.
• W2783297391 hasConcept C68801617 @default.
• W2783297391 hasConcept C69357855 @default.
• W2783297391 hasConcept C82776694 @default.
• W2783297391 hasConcept C86381522 @default.
• W2783297391 hasConcept C97355855 @default.
• W2783297391 hasConceptScore W2783297391C121332964 @default.
• W2783297391 hasConceptScore W2783297391C127413603 @default.
• W2783297391 hasConceptScore W2783297391C147789679 @default.
• W2783297391 hasConceptScore W2783297391C159985019 @default.

• next