FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2783304764> ?p ?o ?g. }

• W2783304764 endingPage "915" @default.
• W2783304764 startingPage "909" @default.
• W2783304764 abstract "CH-π aromatic interactions are ubiquitous in nature and are capable of regulating important chemical and biochemical processes. Solvation and aromatic substituent effects are known to perturb the CH-π aromatic interactions. However, the nature by which the two factors influence one another is relatively unexplored. Here we demonstrate experimentally that there is a quantitative correlation between substituent effects in CH-π interactions and the hydrogen-bond acceptor constants of the solvating molecule. The CH-π interaction energies were measured by the conformational study of a series of aryl-substituted molecular balances in which the conformational preferences depended on the relative strengths of the methyl and aryl CH-π interactions in the folded and unfolded states, respectively. Due to the favorable methyl-aromatic interactions, the balances were found to exist predominantly in the folded state. The observed substituent effect in the conformational preferences of the balances was controlled by the explicit solvation/desolvation of the aryl proton. The interpretation of the conformational free energy as a function of substituents and solvation using Hunter's solvation model revealed that a linear relationship exists between the sensitivity of aromatic substituent effects (i.e., the ρ values derived from Hammett plots) and the hydrogen-bond acceptor propensity (βs) of the solvent molecule: ρ = 0.06βs - 0.04." @default.
• W2783304764 created "2018-01-26" @default.
• W2783304764 creator A5024507421 @default.
• W2783304764 creator A5035392357 @default.
• W2783304764 creator A5039952591 @default.
• W2783304764 creator A5049993872 @default.
• W2783304764 creator A5085169875 @default.
• W2783304764 date "2018-01-23" @default.
• W2783304764 modified "2023-10-14" @default.
• W2783304764 title "Solvent Modulation of Aromatic Substituent Effects in Molecular Balances Controlled by CH−π Interactions" @default.
• W2783304764 cites W1964014905 @default.
• W2783304764 cites W1966689737 @default.
• W2783304764 cites W1969885133 @default.
• W2783304764 cites W1977655765 @default.
• W2783304764 cites W1987919871 @default.
• W2783304764 cites W1988883534 @default.
• W2783304764 cites W1992259310 @default.
• W2783304764 cites W1993468585 @default.
• W2783304764 cites W1998402557 @default.
• W2783304764 cites W1999334659 @default.
• W2783304764 cites W2000827337 @default.
• W2783304764 cites W2006087162 @default.
• W2783304764 cites W2010536094 @default.
• W2783304764 cites W2017449496 @default.
• W2783304764 cites W2020600055 @default.
• W2783304764 cites W2026395206 @default.
• W2783304764 cites W2031865159 @default.
• W2783304764 cites W2044828385 @default.
• W2783304764 cites W2048631643 @default.
• W2783304764 cites W2051238059 @default.
• W2783304764 cites W2086416494 @default.
• W2783304764 cites W2086670418 @default.
• W2783304764 cites W2094186244 @default.
• W2783304764 cites W2095107758 @default.
• W2783304764 cites W2098376669 @default.
• W2783304764 cites W2108290256 @default.
• W2783304764 cites W2117858594 @default.
• W2783304764 cites W2124971322 @default.
• W2783304764 cites W2135564530 @default.
• W2783304764 cites W2142151252 @default.
• W2783304764 cites W2160790360 @default.
• W2783304764 cites W2163758366 @default.
• W2783304764 cites W2163763334 @default.
• W2783304764 cites W2171404207 @default.
• W2783304764 cites W2173122535 @default.
• W2783304764 cites W2195020354 @default.
• W2783304764 cites W2324777999 @default.
• W2783304764 cites W2329776200 @default.
• W2783304764 cites W2331452735 @default.
• W2783304764 cites W2402839684 @default.
• W2783304764 cites W2509606100 @default.
• W2783304764 cites W2535592861 @default.
• W2783304764 cites W2556316013 @default.
• W2783304764 cites W2610460198 @default.
• W2783304764 cites W2610707110 @default.
• W2783304764 cites W4211103670 @default.
• W2783304764 doi "https://doi.org/10.1021/acs.jpca.7b09910" @default.
• W2783304764 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/29332380" @default.
• W2783304764 hasPublicationYear "2018" @default.
• W2783304764 type Work @default.
• W2783304764 sameAs 2783304764 @default.
• W2783304764 citedByCount "14" @default.
• W2783304764 countsByYear W27833047642018 @default.
• W2783304764 countsByYear W27833047642019 @default.
• W2783304764 countsByYear W27833047642020 @default.
• W2783304764 countsByYear W27833047642021 @default.
• W2783304764 countsByYear W27833047642022 @default.
• W2783304764 crossrefType "journal-article" @default.
• W2783304764 hasAuthorship W2783304764A5024507421 @default.
• W2783304764 hasAuthorship W2783304764A5035392357 @default.
• W2783304764 hasAuthorship W2783304764A5039952591 @default.
• W2783304764 hasAuthorship W2783304764A5049993872 @default.
• W2783304764 hasAuthorship W2783304764A5085169875 @default.
• W2783304764 hasConcept C112887158 @default.
• W2783304764 hasConcept C121332964 @default.
• W2783304764 hasConcept C132439834 @default.
• W2783304764 hasConcept C147597530 @default.
• W2783304764 hasConcept C148093993 @default.
• W2783304764 hasConcept C178790620 @default.
• W2783304764 hasConcept C185592680 @default.
• W2783304764 hasConcept C26873012 @default.
• W2783304764 hasConcept C2778689049 @default.
• W2783304764 hasConcept C2779892579 @default.
• W2783304764 hasConcept C2780263894 @default.
• W2783304764 hasConcept C2780471494 @default.
• W2783304764 hasConcept C2781076698 @default.
• W2783304764 hasConcept C32909587 @default.
• W2783304764 hasConcept C71240020 @default.
• W2783304764 hasConceptScore W2783304764C112887158 @default.
• W2783304764 hasConceptScore W2783304764C121332964 @default.
• W2783304764 hasConceptScore W2783304764C132439834 @default.
• W2783304764 hasConceptScore W2783304764C147597530 @default.
• W2783304764 hasConceptScore W2783304764C148093993 @default.
• W2783304764 hasConceptScore W2783304764C178790620 @default.
• W2783304764 hasConceptScore W2783304764C185592680 @default.
• W2783304764 hasConceptScore W2783304764C26873012 @default.
• W2783304764 hasConceptScore W2783304764C2778689049 @default.
• W2783304764 hasConceptScore W2783304764C2779892579 @default.

• next