Matches in SemOpenAlex for { <https://semopenalex.org/work/W2783447925> ?p ?o ?g. }
- W2783447925 endingPage "1454" @default.
- W2783447925 startingPage "1449" @default.
- W2783447925 abstract "Six isostructural antiperovskite-derived chalcohalides, Ba2MQ3X (M = As, Sb; Q = S, Se; X = Cl, Br, I), crystallizing in the space group Pnma, have been synthesized by solid-state reactions. The crystal structure features a 3D framework with the [XBa5]9+ disordered square pyramids as building blocks and [MQ3]3– units filling the interspace. [XBa5]9+ disordered square pyramids are edge-sharing along [010], derived from the fusing of the two pyramids in octahedral [XBa6]11+. Surprisingly, Ba2AsS3X (X = Cl, Br, I) show almost the same optical band gap of 2.80 eV, and Ba2AsSe3X (X = Br, I) also have a similar band gap of 2.28 eV. The optical band gap of Ba2SbS3I is 2.64 eV. First-principles calculations reveal that the optical absorption is attributed to the transitions between Q np at the valence band maximum (VBM) and M np–Q np at the conduction band minimum (CBM). These compounds also possess interesting photoluminescence properties with splitting emission peaks on excitation at 200 nm." @default.
- W2783447925 created "2018-01-26" @default.
- W2783447925 creator A5004970117 @default.
- W2783447925 creator A5020667648 @default.
- W2783447925 creator A5021679611 @default.
- W2783447925 creator A5039995631 @default.
- W2783447925 creator A5044400826 @default.
- W2783447925 creator A5068713433 @default.
- W2783447925 creator A5088796224 @default.
- W2783447925 date "2018-01-08" @default.
- W2783447925 modified "2023-10-16" @default.
- W2783447925 title "Synthesis, Structure, and Optical Properties of Antiperovskite-Derived Ba<sub>2</sub>MQ<sub>3</sub>X (M = As, Sb; Q = S, Se; X = Cl, Br, I) Chalcohalides" @default.
- W2783447925 cites W1970127494 @default.
- W2783447925 cites W1970211301 @default.
- W2783447925 cites W1971215015 @default.
- W2783447925 cites W1975317960 @default.
- W2783447925 cites W1981368803 @default.
- W2783447925 cites W1988998798 @default.
- W2783447925 cites W1997118202 @default.
- W2783447925 cites W2001306804 @default.
- W2783447925 cites W2004029658 @default.
- W2783447925 cites W2007395042 @default.
- W2783447925 cites W2019383577 @default.
- W2783447925 cites W2032980114 @default.
- W2783447925 cites W2033099605 @default.
- W2783447925 cites W2040019268 @default.
- W2783447925 cites W2044116066 @default.
- W2783447925 cites W2044576858 @default.
- W2783447925 cites W2049953774 @default.
- W2783447925 cites W2053732375 @default.
- W2783447925 cites W2056341612 @default.
- W2783447925 cites W2072342320 @default.
- W2783447925 cites W2073960969 @default.
- W2783447925 cites W2079105963 @default.
- W2783447925 cites W2083222334 @default.
- W2783447925 cites W2095570804 @default.
- W2783447925 cites W2189773436 @default.
- W2783447925 cites W2225400667 @default.
- W2783447925 cites W2314863404 @default.
- W2783447925 cites W2327878672 @default.
- W2783447925 cites W2328160373 @default.
- W2783447925 cites W2334093000 @default.
- W2783447925 cites W2412157836 @default.
- W2783447925 cites W2616406765 @default.
- W2783447925 cites W2763482926 @default.
- W2783447925 cites W2949993988 @default.
- W2783447925 cites W2951483115 @default.
- W2783447925 cites W2951922961 @default.
- W2783447925 cites W2952630624 @default.
- W2783447925 doi "https://doi.org/10.1021/acs.inorgchem.7b02812" @default.
- W2783447925 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/29309131" @default.
- W2783447925 hasPublicationYear "2018" @default.
- W2783447925 type Work @default.
- W2783447925 sameAs 2783447925 @default.
- W2783447925 citedByCount "17" @default.
- W2783447925 countsByYear W27834479252018 @default.
- W2783447925 countsByYear W27834479252019 @default.
- W2783447925 countsByYear W27834479252020 @default.
- W2783447925 countsByYear W27834479252021 @default.
- W2783447925 countsByYear W27834479252022 @default.
- W2783447925 crossrefType "journal-article" @default.
- W2783447925 hasAuthorship W2783447925A5004970117 @default.
- W2783447925 hasAuthorship W2783447925A5020667648 @default.
- W2783447925 hasAuthorship W2783447925A5021679611 @default.
- W2783447925 hasAuthorship W2783447925A5039995631 @default.
- W2783447925 hasAuthorship W2783447925A5044400826 @default.
- W2783447925 hasAuthorship W2783447925A5068713433 @default.
- W2783447925 hasAuthorship W2783447925A5088796224 @default.
- W2783447925 hasConcept C115624301 @default.
- W2783447925 hasConcept C120665830 @default.
- W2783447925 hasConcept C121332964 @default.
- W2783447925 hasConcept C147120987 @default.
- W2783447925 hasConcept C168900304 @default.
- W2783447925 hasConcept C178790620 @default.
- W2783447925 hasConcept C181966813 @default.
- W2783447925 hasConcept C185592680 @default.
- W2783447925 hasConcept C193154288 @default.
- W2783447925 hasConcept C194760766 @default.
- W2783447925 hasConcept C198819137 @default.
- W2783447925 hasConcept C205188671 @default.
- W2783447925 hasConcept C26873012 @default.
- W2783447925 hasConcept C27067764 @default.
- W2783447925 hasConcept C2776905175 @default.
- W2783447925 hasConcept C2779227376 @default.
- W2783447925 hasConcept C50792271 @default.
- W2783447925 hasConcept C62520636 @default.
- W2783447925 hasConcept C8010536 @default.
- W2783447925 hasConcept C83581075 @default.
- W2783447925 hasConcept C85080765 @default.
- W2783447925 hasConceptScore W2783447925C115624301 @default.
- W2783447925 hasConceptScore W2783447925C120665830 @default.
- W2783447925 hasConceptScore W2783447925C121332964 @default.
- W2783447925 hasConceptScore W2783447925C147120987 @default.
- W2783447925 hasConceptScore W2783447925C168900304 @default.
- W2783447925 hasConceptScore W2783447925C178790620 @default.
- W2783447925 hasConceptScore W2783447925C181966813 @default.
- W2783447925 hasConceptScore W2783447925C185592680 @default.
- W2783447925 hasConceptScore W2783447925C193154288 @default.