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• W2783454305 abstract "Abstract The syntheses and X-ray structural characterization of four new polymorphs of coordination complexes containing the hydrotris(triazolyl)borate anion, M[BH(trz)3]2 (trz = 1,2,4-trizolate; M = Fe2+, Co2+, Ni2+, Zn2+) are presented. The complexes were characterized by single crystal and powder X-ray diffraction, elemental analysis, and IR spectroscopy. The metal ion is chelated by the endodentate nitrogen atoms of two [BH(trz)3]− ligands and crystallizes in the absence of solvent. The materials are stable in solution and in air. PXRD data indicate that this is the decomposition product of the previously synthesized M[BH(trz)3]2·6H2O. Fe[BH(trz)3]2 is a thermochromic spin-crossover compound with Tsc = 333 K." @default.
• W2783454305 created "2018-01-26" @default.
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• W2783454305 date "2018-03-01" @default.
• W2783454305 modified "2023-09-26" @default.
• W2783454305 title "New polymorphs of hydrotris(1,2,4-triazolyl)borate complexes with M2+ cations (M = Fe, Co, Ni, Zn)" @default.
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• W2783454305 doi "https://doi.org/10.1016/j.ica.2018.01.001" @default.
• W2783454305 hasPublicationYear "2018" @default.
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