FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2783454509> ?p ?o ?g. }

• W2783454509 abstract "Transition-metal-catalyzed alkene hydrosilylation is one of the most important homogeneous catalytic reactions, and the development of methods that use base metals, especially iron, as catalysts for this transformation is a growing area of research. However, the limited number of ligand scaffolds applicable for base-metal-catalyzed alkene hydrosilylation has seriously hindered advances in this area. Herein, we report the use of 1,10-phenanthroline ligands in base-metal catalysts for alkene hydrosilylation. In particular, iron catalysts with 2,9-diaryl-1,10-phenanthroline ligands exhibit unexpected reactivity and selectivity for hydrosilylation of alkenes, including unique benzylic selectivity with internal alkenes, Markovnikov selectivity with terminal styrenes and 1,3-dienes, and excellent activity toward aliphatic terminal alkenes. According to the mechanistic studies, the unusual benzylic selectivity of this hydrosilylation initiates from π-π interaction between the phenyl of the alkene and the phenanthroline of the ligand. This ligand scaffold and its unique catalytic model will open possibilities for base-metal-catalyzed hydrosilylation reactions." @default.
• W2783454509 created "2018-01-26" @default.
• W2783454509 creator A5000300529 @default.
• W2783454509 creator A5021740792 @default.
• W2783454509 creator A5027810344 @default.
• W2783454509 creator A5053014464 @default.
• W2783454509 creator A5054729890 @default.
• W2783454509 creator A5055273759 @default.
• W2783454509 creator A5067882591 @default.
• W2783454509 creator A5087391793 @default.
• W2783454509 date "2018-01-15" @default.
• W2783454509 modified "2023-10-17" @default.
• W2783454509 title "Ligands with 1,10-phenanthroline scaffold for highly regioselective iron-catalyzed alkene hydrosilylation" @default.
• W2783454509 cites W1164967805 @default.
• W2783454509 cites W1985476296 @default.
• W2783454509 cites W1989807773 @default.
• W2783454509 cites W2017239055 @default.
• W2783454509 cites W2022806379 @default.
• W2783454509 cites W2024099693 @default.
• W2783454509 cites W2054983676 @default.
• W2783454509 cites W2058239145 @default.
• W2783454509 cites W2066508684 @default.
• W2783454509 cites W2067886511 @default.
• W2783454509 cites W2072750040 @default.
• W2783454509 cites W2080727882 @default.
• W2783454509 cites W2089923076 @default.
• W2783454509 cites W2093371352 @default.
• W2783454509 cites W2100769852 @default.
• W2783454509 cites W2109679704 @default.
• W2783454509 cites W2123515993 @default.
• W2783454509 cites W2146674250 @default.
• W2783454509 cites W2157385965 @default.
• W2783454509 cites W2161999177 @default.
• W2783454509 cites W2237079072 @default.
• W2783454509 cites W2253330152 @default.
• W2783454509 cites W2290027198 @default.
• W2783454509 cites W2312414376 @default.
• W2783454509 cites W2313002646 @default.
• W2783454509 cites W2323198075 @default.
• W2783454509 cites W2326068625 @default.
• W2783454509 cites W2329412046 @default.
• W2783454509 cites W2335246962 @default.
• W2783454509 cites W2344216722 @default.
• W2783454509 cites W2402183164 @default.
• W2783454509 cites W2468515422 @default.
• W2783454509 cites W2474436892 @default.
• W2783454509 cites W2495361167 @default.
• W2783454509 cites W2502527976 @default.
• W2783454509 cites W2515971915 @default.
• W2783454509 cites W2518629815 @default.
• W2783454509 cites W2521473510 @default.
• W2783454509 cites W2559531192 @default.
• W2783454509 cites W2571374444 @default.
• W2783454509 cites W2578984193 @default.
• W2783454509 cites W2589662445 @default.
• W2783454509 cites W2605500166 @default.
• W2783454509 cites W2607183661 @default.
• W2783454509 cites W2729944282 @default.
• W2783454509 cites W4239321948 @default.
• W2783454509 doi "https://doi.org/10.1038/s41467-017-02472-6" @default.
• W2783454509 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/5768772" @default.
• W2783454509 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/29335560" @default.
• W2783454509 hasPublicationYear "2018" @default.
• W2783454509 type Work @default.
• W2783454509 sameAs 2783454509 @default.
• W2783454509 citedByCount "131" @default.
• W2783454509 countsByYear W27834545092018 @default.
• W2783454509 countsByYear W27834545092019 @default.
• W2783454509 countsByYear W27834545092020 @default.
• W2783454509 countsByYear W27834545092021 @default.
• W2783454509 countsByYear W27834545092022 @default.
• W2783454509 countsByYear W27834545092023 @default.
• W2783454509 crossrefType "journal-article" @default.
• W2783454509 hasAuthorship W2783454509A5000300529 @default.
• W2783454509 hasAuthorship W2783454509A5021740792 @default.
• W2783454509 hasAuthorship W2783454509A5027810344 @default.
• W2783454509 hasAuthorship W2783454509A5053014464 @default.
• W2783454509 hasAuthorship W2783454509A5054729890 @default.
• W2783454509 hasAuthorship W2783454509A5055273759 @default.
• W2783454509 hasAuthorship W2783454509A5067882591 @default.
• W2783454509 hasAuthorship W2783454509A5087391793 @default.
• W2783454509 hasBestOaLocation W27834545091 @default.
• W2783454509 hasConcept C116569031 @default.
• W2783454509 hasConcept C118792377 @default.
• W2783454509 hasConcept C142724271 @default.
• W2783454509 hasConcept C161790260 @default.
• W2783454509 hasConcept C170493617 @default.
• W2783454509 hasConcept C178790620 @default.
• W2783454509 hasConcept C185592680 @default.
• W2783454509 hasConcept C204787440 @default.
• W2783454509 hasConcept C21951064 @default.
• W2783454509 hasConcept C2776254738 @default.
• W2783454509 hasConcept C2776910235 @default.
• W2783454509 hasConcept C2777660389 @default.
• W2783454509 hasConcept C2778421718 @default.
• W2783454509 hasConcept C55493867 @default.
• W2783454509 hasConcept C59759590 @default.
• W2783454509 hasConcept C71924100 @default.
• W2783454509 hasConceptScore W2783454509C116569031 @default.
• W2783454509 hasConceptScore W2783454509C118792377 @default.

• next