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- W2783456073 abstract "Solar energy conversion via internal photoemission (IPE) across a planar p-type Schottky junction is quantified for aluminum (Al) and copper (Cu) in the framework of direct transitions with non-constant matrix elements. Transition probabilities and k-resolved group velocities are obtained based on pseudo-wavefunction expansions and realistic band structures using the pseudopotential method. The k-resolved number of direct transitions, hole photocurrent density, quantum yield (QY), and the power conversion efficiency (PCE) under AM1.5G solar irradiance are subsequently calculated and analyzed. For Al, the parabolic and “parallel-band” effect along the U-W-K path significantly enhances the transition rate with final energies of holes mainly within 1.41 eV below the Fermi energy. For Cu, d-state hot holes mostly generated near the upper edge of 3d bands dominate the hole photocurrent and are weekly (strongly) dependent on the barrier height (metal film thickness). Hot holes produced in the 4s band behave jus..." @default.
- W2783456073 created "2018-01-26" @default.
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- W2783456073 date "2018-01-14" @default.
- W2783456073 modified "2023-09-23" @default.
- W2783456073 title "Internal photoemission for photovoltaic using <i>p</i>-type Schottky barrier: Band structure dependence and theoretical efficiency limits" @default.
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- W2783456073 doi "https://doi.org/10.1063/1.5003117" @default.
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