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- W2783456440 abstract "Toward high-temperature lithium-ion batteries, adding inorganic materials are proposed as an effective strategy. However, inorganic particles tend to aggregate in the polymer matrix, causing degradation in battery performance. Here, a PVDF-HFP/colloidal Al2O3 composite separator is prepared with a phase inverse method. The colloidal Al2O3 particles well dispersed in the PVDF-HFP polymer matrix substantially enhance the mechanical strength of the PVDF-HFP separator. The PVDF-HFP/colloidal Al2O3 composite separator owns a high electrolyte uptake of 372%, a high ionic conductivity of 1.3 × 10−3 S cm−1 at 80 °C and delivers high capacity retention of 95.6% after 100 charge–discharge cycles at 0.5 C. In addition, PVDF-HFP/colloidal Al2O3 separator only has a 4.5% thermal shrinkage at 150 °C and exhibits high electrochemical performances upon annealing at 140 °C." @default.
- W2783456440 created "2018-01-26" @default.
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- W2783456440 date "2018-01-11" @default.
- W2783456440 modified "2023-10-17" @default.
- W2783456440 title "Highly Efficient PVDF-HFP/Colloidal Alumina Composite Separator for High-Temperature Lithium-Ion Batteries" @default.
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- W2783456440 doi "https://doi.org/10.1002/admi.201701147" @default.
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