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• W2783457928 abstract "Herein, a series of GdSr2AlO5:Tb3+,Eu3+ phosphors were successfully synthesized through a high temperature solid-state reaction, and their crystal structures as well as photoluminescence properties were investigated in detail. Compared to the intense emission of 5D0 → 7F1 or 5D0 → 7F2 transition of Eu3+, another strong emission corresponding to 5D0 → 7F4 was observed. Concentration quenching is not obvious in Tb3+ or Eu3+-doped GdSr2AlO5 because structure isolation and energy transfer (ET) of Gd3+ → Eu3+ and Gd3+ → Tb3+ were found. Moreover, the energy transfer process from Tb3+ to Eu3+ was verified by the overlap of luminescence spectra and the variation of lifetime. Energy transfer mechanism was determined to be a dipole-dipole interaction, and ET efficiency as well as quantum efficiency were also obtained. Moreover, the emission color of GdSr2AlO5:Tb3+,Eu3+ can be tuned from green to red by altering the ratio of Tb3+/Eu3+. These results indicate that the GdSr2AlO5:Tb3+,Eu3+ phosphor is a promising single-component white light-emitting phosphor." @default.
• W2783457928 created "2018-01-26" @default.
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• W2783457928 date "2018-01-01" @default.
• W2783457928 modified "2023-10-14" @default.
• W2783457928 title "Tunable emission from green to red in the GdSr₂AlO₅:Tb³⁺,Eu³⁺phosphor<i>via</i>efficient energy transfer" @default.
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• W2783457928 doi "https://doi.org/10.1039/c7ra12260h" @default.
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